Results: All materials tested demonstrated different degrees of sorption and solubility. The glass ionomer cement had the best value for sorption. The zinc oxide eugenol and eugenol free cements had lower water sorption than the zinc polycarboxylate and zinc phosphate cements were evaluated. Some materials retained water in their structure and thus compensated for any loss of mass due to dissol...

The previously-obtained and characterized hybrid pectin-based beads containing agar-agar and guar gum, as well as sole pectin beads (P, for comparison) were examined for zinc ions sorption and desorption properties. The sorption kinetics and equilibrium in the studied system was described by two kinetic models (pseudo-first- and pseudo-second-order) and two isotherms (Langmuir and Freundlich), ...

A bis(phosphonatemonoester) is employed as a linker in a Zn(II) metal organic framework. The complex is a layered structure pillared only by vdW interactions between alkyl groups. Nonetheless, permanent pores are formed as confirmed by PXRD and gas sorption analysis.

In this study, waste olive cake (OC) was utilized as the raw material for the production of biosorbents by chemical treatment and its adsorption capacity for zinc ion was evaluated. Tests were conducted with the total biomass (T) and with the fraction > 2.00 mm (P), in order to determinate the influence of this fractionation step on subsequent treatments. Two chemical agents were used: sulfuric...

Elucidating the reaction mechanisms and estimating the associated transport and thermodynamic parameters are important for an accurate description of the fate of toxic metal pollutants, such as Zn(II), in soils and aquatic ecosystems rich in iron oxides. Consequently, sorption of Zn(II) ions onto ferrihydrite was investigated with macroscopic and spectroscopic studies as a function of pH (4.0-8...

the kinetics of zn sorption by ten calcareous soils of iran were measured and fitted to several equations (zero-, first-, second-, third-order, parabolic diffusion, simple elovich, and exponential equations). two initial concentrations of zinc i.e. 20 and 80 mg zn l-1 were used and observations were carried out for 100 hours. the time required to reach the near equilibrium state was about 24 ho...

several factors effect on sorption of polycyclic aromatic hydrocarbons (pahs) in soil. co-existence of metals and organic matter of soil are among important affecting factors on sorptive behavior of pahs. this research investigated the effect of organic matter content and heavy metals (lead, nickel and zinc), on sorption of phenanthrene onto kaolinite. for this purpose, sorption of the organic ...

Several factors effect on sorption of polycyclic aromatic hydrocarbons (PAHs) in soil. Coexistence of metals and organic matter of soil are among important affecting factors on sorptive behavior of PAHs. This research investigated the effect of organic matter content and heavy metals (lead, nickel and zinc), on sorption of phenanthrene onto kaolinite. For this purpose, sorption of the organic m...

The new one-pot hydrolysis-crosslinking reaction was used to synthesize a new, waste poly(methyl methacrylate) (PMMA)-based material for zinc(II) ions removal. The alkaline hydrolysis of PMMA in diethylene glycol diethyl ether was used to obtain polymer matrix and it was then crosslinked with Ca and Mg ions to obtain the sorbent. As a result, the macroporous materials were obtained with a yield...

The effects of zinc and manganese on the reductive dissolution of hematite by the dissimilatory metal-reducing bacterium (DMRB) Shewanella putrefaciens CN32 were studied in batch culture. Experiments were conducted with hematite (2.0 g L 1) in 10 mM PIPES (pH 6.8), and H2 as the electron donor under nongrowth conditions (108 cell mL 1), spiked with zinc (0.02–0.23 mM) or manganese (0.02–1.8 mM)...