A solvent-extraction spectrophotometric technique is proposed as a new method for determination of trace quantities of vanadium. Sodium salt of 2-mercapto-pyridine-N-oxide (thione) forms a complex with vanadium instantaneously. The purple 1:2 complex is formed of pH 2.3, easily extracted in chloroform and shows strong absorbance at 500 nm. The extracted complex is found to obey Beer's law i...

a simple and sensitive extractive- spectrophotometric method for thedeterrnination of trace amounts of vanadium(v) is reported. the method is based on the quantitative extraction of the anion complex of v(v) with 4-(2-pyridy1azo)-resorcinol with tetrabutylammonium perchlorate into chloroform, followed by spectrophotometric measurements at 554 nm. beer's law is obeyed over the concentration...

A sensitive and simultaneous spectrophotometric flow injection method for the determination of vanadium(IV) and vanadium(V) is proposed. The method is based on the effect of ligands such as 2,4,6-tris(2-pyridyl)-1,3,5-triazine (TPTZ) and diphosphate on the conditional redox potential of iron(III)/iron(II) system. A four-channel flow system is assembled. In this flow system, diluted hydrochloric...

Vanadium (III) gives a greenish- yellow complex with anthranilic acid in presence of pyridine. The complex is extractable with chloroform and is used for photometric determination of vanadium by measuring the absorbance at 390 nm against a reagent blank. Beer's Law holds good in the range of 1-20 pg V/ml. Moderate amounts of Pb (II) , Ca (II) , Sr (II) , Ba (II) , Cd (II) , Mg (II) , Mn (II...

The ubiquity of vanadium oxo complexes in the V+ and IV+ oxidation states has contributed to a comprehensive understanding of their electronic structure and reactivity. However, despite being predicted to be stable by ligand-field theory, the isolation and characterization of a well-defined terminal mononuclear vanadium(III) oxo complex has remained elusive. We present the synthesis and charact...

A simple and sensitive extractive- spectrophotometric method for thedeterrnination of trace amounts of vanadium(V) is reported. The method is based on the quantitative extraction of the anion complex of V(V) with 4-(2-pyridy1azo)-resorcinol with tetrabutylammonium perchlorate into chloroform, followed by spectrophotometric measurements at 554 nm. Beer's law is obeyed over the concentration ...

A series of vanadium(V) complexes with o-dioxolene (catecholato) ligands and an ancillary ligand, (N-(salicylideneaminato)ethylenediamine) (hensal), were investigated using 51V solid-state magic angle spinning NMR spectroscopy (51V MAS NMR) to assess the local environment of the vanadium(V). The solid-state 51V NMR parameters of vanadium(V) complexes with a related potentially tetradentate anci...

The reaction of the oxidovanadium(V) complexes with N,N-dimethylhydrazine was demonstrated to afford the corresponding vanadium(V) dimethylhydrazido complexes. The substituent at the 3-position of the tris(2-hydroxyphenyl)amine ligand was found to influence the electronic environment of the vanadium center. The crystal structure of the non-substituted vanadium(V) dimethylhydrazido complex exhib...

The aim of the present study is to synthesize the oxovanadium complex of the V3+ ion with isatin sciff bases. Spectroscopic methods have been used to confirm these models of complexation and to understand the structures of the species formed in methanolic solution. We also have isolated a complex of Vanadium (III) with isatin schiff bases in the solid phase.

Solid-phase spectrophotometry has been applied to analysis for trace amounts of vanadium. Vanadium was sorbed in a styrene-divinylbenzene-type anion-exchanger Dowex 1-X8 as a vanadium-4-(2-pyridylazo)resorcinol complex. Resin phase absorbances at 562 and 800 nm were measured directly which allowed the determination of vanadium in the range of 0.1-2.4 ng/ml with a RSD of 1.5%. The method has bee...