For the first time, both X-ray Photoelectron Spectroscopy (XPS) and Auger Electron Spectroscopy (AES) techniques were applied in analysis of surface contamination of electrochemically etched Scanning Tunneling Microscope (STM) tungsten tips. Carbon monoxide, graphite, tungsten carbide and tungsten oxide were found as main surface contaminations of STM tungsten tips. The thickness of tungsten ox...

The use of a molecular gold organometallic cluster in chemical vapour deposition is reported, and it is utilized, together with a tungsten oxide precursor, for the single-step co-deposition of (nanostructured) tungsten oxide supported gold nanoparticles (NPs). The deposited gold-NP and tungsten oxide supported gold-NP are highly active catalysts for benzyl alcohol oxidation; both show higher ac...

Here, we report that the postsynthesis nitridation of tungsten oxide nanowires can result in single crystal nitride nanowires when the initial diameters of the nanowires are less than 10 nm. For nanowires with diameters greater than 10 nm, the nitridation of nanowires resulted in polycrystalline but highly oriented tungsten nitride domains in nanowires. Partially nitrided nanowires show an epit...

This paper describes a method for producing tungsten oxide nanostructues in an environmental scanning electron microscope. The growth is observed in real time and offers direct observation of the morphology of the tungsten oxide condensed onto the cooler part of a typical W Scanning Electron Microscope filament. We also find that the growth of nanostructures occurs on timescales much shorter th...

In the present study, tungsten oxide nanomaterials were synthesized by a modified plasma arc gas condensation technique. The effects of processing parameters (plasma current ranged from 70-90 A and chamber pressure ranged from 200-600 torr) on the preparation of tungsten oxide nanomaterials were investigated. X-ray diffraction results showed that all of the nanomaterials synthesized in the pres...

We investigated the photocbromic (PC) and electrocbromic (EC) behavior of sputtered tungsten oxide (W03_1) films with different oxygen deficiency y. It was found that both the PC and EC coloration efficiency increase with increasing oxygen deficiency in tungsten oxide. For PC efficiency, this behavior is consistent with the model of photocbromism developed recently. A recently developed model b...

A series of model-supported WO3 catalysts were synthesized on preformed Al2O3, Nb2O5, TiO2, and ZrO2 supports by impregnation of aqueous ammonium metatungstate, (NH4)10W12O41·5H2O. The molecular and electronic structures of the supported tungsten oxide phases were determined with in situ Raman and UV–vis spectroscopy, respectively. The supported tungsten oxide structures are the same on all oxi...

new type of heterogeneous nanocatalyst for deoximation based on tungsten oxide supported on mesoporousmolecular sieve mcm-41 was developed. this new system representes inexpensive and highly activeheterogeneous nanocatalyst for deoximation under green and mild reaction conditions.

Tungsten oxide/tungsten sulfide (W18O49@WS2) core-shell nanorods prepared via a controlled sulfidization reaction of W18O49 nanowhiskers showed hydrogen evolution reaction (HER) activity superior to WS2 nanotubes, indicating the critical role of a highly conductive oxide core in enhancing HER activity.

Composite materials: Tungsten disulfide and WS2 /reduced graphene oxide (WS2 /rGO) nanosheets were fabricated by hydrothermal synthesis using tungsten chloride, thioacetamide, and graphene oxide (GO) as starting materials. The WS2 nanosheets are efficiently templated on the rGO layer. The WS2 /rGO hybrid nanosheets show much better electrocatalytic activity for the hydrogen evolution reaction t...