iron is quantitatively retained on an adsorbent made by coprecipitation of 1,2-dihydroxybenzene-3,5-disulfonic acid (tiron) and tetradecyldimethylbenzylammonium choride (tdba) an microcrystalline naphthalene as a slurry or packed in a column, in the ph range 6.0-9.0 from a large volumes of aqueous solutions (up to 200 ml on microcrystalline naphthalene and up to 500 ml of aqueous solutions in t...

A new, simple, sensitive and selective method for the simultaneous determination of trace iron and aluminum by catalytic spectrophotometry was presented, based on the catalytic effects of iron and aluminum on the discoloring reaction of xylene cyanol FF proceeded by hydrogen peroxide and potassium periodate in weak nitric acid medium. No catalytic effect was obtained in the presence of hydrogen...

An advanced stopped-in-loop flow analysis (SILFA) is proposed for the catalytic determinations of vanadium and iron. The chemistry relies on a vanadium- or iron-catalyzed oxidative reaction of p-anisidine by bromate or hydrogen peroxide in the presence of an activator (Tiron or 1,10-phenanthlorine) to form a red dye (510 nm). Reagents for the vanadium- or iron-catalyzed reaction are well mixed ...

A simple, selective and highly sensitive extraction method has been developed for the determination of iron(II) spectrophotometrically after solid phase extraction. The absorbance is measured at λmax 644 nm. Beer's law was obeyed up to 450 ng mL(-1) of iron. The molar absorptivity, Sandell's sensitivity, detection and quantification limits were calculated and found to be 1.09×10(5) L mol(-1) cm...

A kinetic-catalytic spectrophotometric flow-injection method was developed for the rapid and sensitive determination of trace amounts of copper(II). The method is based on the catalytic effect of copper(II) on the redox reaction of cysteine with iron(III). Iron(II) produced by the catalytic reaction reacts with 2,4,6-tris(2-pyridyl)-1,3,5-triazine (TPTZ) to form the iron(II)-TPTZ complex (lambd...