A new unsymmetric thioether diamine N - ( 2 - ( 2 - aminophenylthio) ethyl) benzene - 1 , 2 - diamine was prepared through the nucleophilic substitution of cysteaminium chloride with 1 - chloro - 2 - nitrobenzene and then the nitro groups of prepared compuond converted to the amine by zinc powder and ammonium chloride. Then, unsymmetric Schiff bass ligand 2 - ((( 2 - (( 2 - (( 2 - (( 2 - hydrox...

Heteroleptic copper complexes containing an acetylacetonato ligand and a thioether derivatized dipyrrinato ligand are shown to form oligomers and polymers in the solid state.

A pyridine and thioether co-supported triazole ligand L (L = 2-((4-(3-(cyclopentylthio)propyl) -1H-1,2,3-triazol-1-yl)methyl)pyridine) has been synthesized using the CuAAC click reaction. This ligand supports the formation of a thermally stable, one-dimensional coordination polymer [L2Ag4]n·4n(BF4) (1) possessing a cationic polymeric structure with [Ag4] metallomacrocycles, in which the ligand ...

We have investigated the coordination modes of NNS Schiff base, thioether ligands to manganese(I) carbonyls. The ligands contain ortho substituted pyridines (H, CH3, OCH3, fluorophenyl) and varying substituents (H, CH3) at the Schiff base linkage. In general, reaction of [Mn(CO)5Br] with a tridentate NNS ligand in CH2Cl2 affords species in which the thioether-S may be bound or unbound to the ma...

Thioether-phosphite ligands (SP’s) with axially chiral (S)-H0- or (S)-H8-binaphthyl moiety and their [Rh(COD)(SP)]BF4 complexes have been synthesized to study coordination chemistry catalytic features compare them those of the structurally analogous phosphine-phosphites (PP’s). NMR exchange studies on showed selective 1,5-cyclooctadiene dynamics. Firm evidence has found that this fluxional proc...

The activation of dioxygen by dopamine beta-monooxygenase (DbetaM) and peptidylglycine alpha-hydroxylating monooxygenase (PHM) is postulated to occur at a copper site ligated by two histidine imidazoles and a methionine thioether, which is unusual because such thioether ligation is not present in other O2-activating copper proteins. To assess the possible role of the thioether ligand in O2 acti...

This paper reports on the synthesis, characterization and electrochemical properties of four ferrocenylmethyl substituted L-amino acid ligands and their Cu(II) complexes. Structural characterization of the complexes of L-methionine and L-asparagine derived ligands showed axial coordination of weak thioether and amide respectively to Cu(II). Coordination of the thioether group of L-methionine to...

Effective methods of ligand design have been highly sought due to the significant roles of ligands in controlling metal catalyses. In particular, easy-to-handle ligands to realize high reaction efficacy, substrate tolerance, and environmental friendliness are desirable. Novel bidentate ligands containing N-heterocyclic carbene and thioether moieties were developed based on findings of hemilabil...

The non-heme iron complexes, [Fe(II)(N3PySR)(CH3CN)](BF4)2 () and [Fe(II)(N3Py(amide)SR)](BF4)2 (), afford rare examples of metastable Fe(iii)-OOH and Fe(iii)-OOtBu complexes containing equatorial thioether ligands and a single H-bond donor in the second coordination sphere. These peroxo complexes were characterized by a range of spectroscopic methods and density functional theory studies. The ...

Several N-functionalized bis(phosphino)amine ligands with ether, thioether and pyridyl tethers [(R'')2PN(R')P(R'')2=PNP] () have been synthesized. They react with CrCl3(THF)3 in CH2Cl2 to give dinuclear chloro bridged Cr2(micro-Cl)2Cl4(PNP)2 () which converts to the corresponding mononuclear solvento complexes fac-CrCl3(PNP)(NCR) (). The structures of the ligand with R'=-(CH2)3SCH3 and R''=Ph, ...