نتایج جستجو برای: thioacetalization
تعداد نتایج: 13 فیلتر نتایج به سال:
We report here the first catalytic asymmetric thioacetalization of salicylaldehyde and dithiol. Chiral phosphoric acid STRIP C5 is identified as a powerful catalyst for this reaction to afford various chiral dithioacetals in high to excellent yields and enantioselectivities under mild conditions.
nano-silica supported boron trifluoride (bf3.sio2) is an efficient, reusable and eco-friendly catalyst for chemoselective thioacetalization of aldehydes and ketones. so, this catalyst was applied for transthioacetalization of acetals and acylals into their corresponding 1,3-dithiolanes or 1,3-dithianes in good to excellent yields. the reactions were carried out at room temperature under solven...
selective desulfurization of thiocarbonyls to carbonyls thioacetalization of aldehydes and ketones a useful reagent system for the dethioacetalization reactions
Nano-silica supported boron trifluoride (BF3.SiO2) is an efficient, reusable and eco-friendly catalyst for chemoselective thioacetalization of aldehydes and ketones. So, this catalyst was applied for transthioacetalization of acetals and acylals into their corresponding 1,3-dithiolanes or 1,3-dithianes in good to excellent yields. The reactions were carried out at room temperature under solven...
Nano-silica supported boron trifluoride (BF3.SiO2) is an efficient, reusable and eco-friendly catalyst for chemoselective thioacetalization of aldehydes and ketones. So, this catalyst was applied for transthioacetalization of acetals and acylals into their corresponding 1,3-dithiolanes or 1,3-dithianes in good to excellent yields. The reactions were carried out at room temperature under solven...
An attempt to synthesize the cyclohexane core of antibiotic abyssomicin C is described. The initial, protecting group-free approach (relying on internal protection) failed and had be modified, in order allow for efficient deprotection acid-sensitive cyclization precursor penultimate synthetic step. Thus, a pyranoside structural unit was used as latent lactone/ester functionality, which deprotec...
Acetalization of benzaldehyde and substituted benzaldehydes (containing both electron-donating and electron-withdrawing groups) is explained qualitatively on the basis of global electrophilicity descriptor, w, as proposed by Parr and coworkers. The generated values of w can explain qualitatively the preferential electrophilic addition, and hence, the yield of acetalization obtained in an earlie...
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