in this paper, the performance of a natural gas hcci engine is studied through a thermodynamic model including detailed chemical kinetics. it is shown that as hydroxyl radical has important effects on natural gas combustion, it is possible to quantify soc with hydroxyl concentration variations. meanwhile the influence of using formaldehyde as an additive on the engine characteristics has been i...

The question on the effectiveness of geometrical methods for development and interpretation of extreme thermodynamic models is evidently subject to essential subjectivism and partiality. So, whereas Newton in his Principles started to solve each of more than 200 considered problems with graphical explanations, and only then passed to formulas, Lagrange in Mechanique Analytique did not present a...

experimental determination of solubility and ternary phase diagram of chiral compound are of tedious and time consuming tasks, and in many cases, there is not enough experimental data for different enantiomeric compositions to access the experimental ternary phase diagram. using thermodynamic models with predictive capability, having less dependency on experimental data, affords a great advanta...

combined cycle performance can be improved by improving the performance of gas turbine based topping cycle. amongst various options the effective cooling of gas turbine blade for realizing the higher turbine inlet temperatures is one of the attractive options. the present paper deals with the thermodynam-ic analysis of advanced technology gas/steam combined cycle based power plant having closed...

Bayerite is one of the phases of aluminum hydroxide which is precipitated by the carbonation of aluminate solutions obtained from sintered nepheline syenite leaching. In this study, the conditions for the bayerite formation were predicted by thermodynamic modeling of the carbonation process and the Bromley- Zemaitis model was used for this purpose. Carbonation experiments were carried out a...

Modeling atmospheric aerosols containing a large organic fraction with unknown chemical composition and properties has been a constant challenge. The dissertation focuses on the theoretical treatment of the thermodynamic equilibrium of atmospheric aerosol involving organic species. We present a vapor pressure estimation method, based on quantum chemistry methods, to predict the liquid vapor pre...