thermal cracking of a heavy liquid hydrocarbon was performed in a laboratory scale tubular reactor. central composite design (ccd), was used as an experimental design method. the design variables were coil outlet temperature (cot), feed flow and rate steam ratio. maximum yield of ethylene was 30.37 wt% at cot, residence time and steam ratio of 869oc, 0.208 s and 1.22 g/g, respectively. maximum ...

It is broadly accepted that so-called 'thermal' gas is the product of thermal cracking, 'primary' thermal gas from kerogen cracking, and 'secondary' thermal gas from oil cracking. Since thermal cracking of hydrocarbons does not generate products at equilibrium and thermal stress should not bring them to equilibrium over geologic time, we would not expect methane, ethane, and propane to be at eq...

Abstract Simulation of heavy oil thermal cracking process is very important but few researches have been published now. In this paper, a simulation framework based on the carbon number-based approach(CNCA) has been established. A systematic division rule is put forward for dividing cracked products into 59 carbon number components. Then the cracking reaction network has been structured and the ...

The susceptibility of structural concrete to early-age cracking depends on material composition, methods of processing, structural boundary conditions, and a variety of environmental factors. Computational modeling offers a means for identifying primary factors and strategies for reducing cracking potential. Herein, lattice models are shown to be adept at simulating the thermal-hygral-mechanica...

[1] The development of transient thermal stress in suboceanic mantle is investigated on the basis of two-dimensional thermoviscoelastic models incorporating composite rheology appropriate for dry oceanic lithosphere. Thermal stress is shown to be sufficiently high to deeply fracture the coldest part of lithosphere, e.g., to the depth of at least 30 km (and possibly down to 50 km) in 100-Ma-old ...

The thermal cracking of hydrocarbons for olefin production is carried out in long tubular reactors inserted in a furnace, in this process the heat flux along the reactor wall determines the feedstock conversion, the olefin selectivity's and rate of coke deposition. A detailed firebox simulation model is therefore a powerful tool in the design and operation of pyrolysis furnaces and reactors to ...

Allothermal cracking of methane is a suitable and eco-friendly way to simultaneously produce hydrogen and carbon black. The economic viability of the process relies on the ability to produce carbon black having well-defined characteristics, particularly concerning the particle size. A model for the study of the carbon particle size distribution during thermal cracking of methane has been develo...

in thermal cracking plants, it is desired to apply an optimal temperature profile along the reactor to minimize the operation cost. in this article a simulator is developed by the use of a mathematical model, which describes the static operation of a naphtha thermal cracking pilot plant. the model is used to predict the steady state profiles of the gas temperature and product yields. using a dy...

SHAHAB is a PC- based simulator developed by Olefin Research Group (ORG), with the simultaneous simulation of the reactor, the firebox, the convection section and the transfer line exchanger in steam Cracking units. The reaction mechanism of thermal cracking of hydrocarbons is generally accepted as free-radical chain reactions. Using a rigorous kinetic model, a complete reaction network for rep...