Crystal structure and compressibility of potassium azide was investigated by in-situ synchrotron powder X-ray diffraction in a diamond anvil cell at room temperature up to 37.7 GPa. In the bodycentered tetragonal (bct) phase, an anisotropic compressibility was observed with greater compressibility in the direction perpendicular to the plane containing N3 ions than directions within that plane. ...

The microstructure and morphology of solid-oxide fuel-cell electrodes are very complex but important because they strongly affect the electrical performance of the cell. In this work the high-resolution X-ray nanotomography technique is applied to reconstruct the three-dimensional microstructure of a (La(0.8)Sr(0.2))(0.95)MnO(3) yttria-stabilized zirconia composite cathode. Some key microstruct...

a hydrothermal method for preparation of nano-size zirconia has been studied to optimize the effective parameters (precursor concentration, temperature and time) using response surface methodology (rsm). the synthesized zirconia samples were characterized through x-ray diffraction (xrd), scanning electron microscope (sem) and transmission electron microscopy (tem) analyses to identify mean nano...

We have investigated the nanoscale switching properties of strain-engineered BiFeO(3) thin films deposited on LaAlO(3) substrates using a combination of scanning probe techniques. Polarized Raman spectral analysis indicates that the nearly tetragonal films have monoclinic (Cc) rather than P4mm tetragonal symmetry. Through local switching-spectroscopy measurements and piezoresponse force microsc...

the stabilized zirconia with different cu contents synthesized via sol-gel method. the samples were prepared by hydrolysis and condensation of orgnomatelic sol. after that the result gels were dried at 80 °c and then calcined at various temperatures.  ِ the differential thermal analysis (dta), x-ray diffraction (xrd), field emission scanning electronic microscopy (fesem) and transmission electro...

The tetragonal states produced by isotropic pseudomorphic epitaxial strain in the ~001! plane on a tetragonal phase of a crystal are calculated for V, Ti, Rb, Li, K, and Sr from first-principles electronic theory. It is shown that each metal has two tetragonal phases corresponding to minima of the total energy with respect to tetragonal deformations ~and hence are equilibrium phases! and that t...

Diierent bounds on the conductivity of a composite material may improve on each other in diierent conductivity regimes. If so, the question arises of how to eeciently interpolate between the bounds. In this paper we show how to do an interpolation with a two-point Pad e approximation method. For bounds on two-component composites the interpolation method is shown to be, in a sense, the best pos...

‘Lattice parameters determined from the synchrotron X-ray diffraction scans of the cubic 200 and tetragonal 220/004 Bragg peaks. Fits to the cubic lattice parameter (black solid line) and the average tetragonal lattice parameter (= 2atet + ctet)/3 (blue solid line), were used to determine the linear coefficients of thermal expansion of 1.95 × 10−4 K−1 (cubic) and 2.66 × 10−4 K−1 (tetragonal). T...

objective: a clinical challenge of using zirconia frameworks is to achieve adequate bond with different substrates. this study aimed to evaluate the effect of bioglass and silica coating of zirconia substrates on microshear bond strength of resin cement to tetragonal zirconia. methods: this laboratory experimental study was conducted on zirconia discs. a total of 120 ytzp zirconia (zirkonzahn) ...

Yttria-stabilized tetragonal zirconia polycrystals (Y-TZP) have proved to be important structural ceramics. High strength and fracture toughness make them attractive candidates for a number of demanding applications. It was established that these advantageous properties are strongly influenced by the ceramic microstructure [1]. The relationships between microstructure and mechanical properties ...