the potential of heat inactivated saccharomyces cerevisiae in the bioremoval and reduction ofcr (vi) ions from wastewaters was evaluated in terms of metal uptake in time and at equilibrium, andbiosorption efficiency, by varying ph, biosorbent doses, contact time and temperature, in batch mode. during the sorption process, the heat inactivated biomass of the yeast saccharomyces cerevisiae is cap...

Varied temperature sublimation of calix[5]arene results in the formation of two distinctly different crystal structures or polymorphs alpha and beta, the latter of which is based on both 'self-included' and 'back-to-back' helical arrangements of the molecule, while also being active towards CO2 sorption at room temperature and 1 atmosphere pressure.

The synthesis and successful activation of IRMOF-8 (Zn(4)O(ndc)(3), ndc = naphthalene-2,6-dicarboxylate) is presented. Room temperature synthesis effectively suppresses interpenetration. Although conventional activation under reduced pressure leads to structural collapse, activation by flowing supercritical CO(2) yields a guest-free material with a BET surface area of 4461 m(2) g(-1).

The kinetics of chromium ions sorption from aqueous solution on fungi biomass have been investigated in a batch system. The experimental data were analysed based on an intraparticle diffusion equation and a pseudo-second-order mechanism, in order to predict the constant rate of sorption and the equilibrium capacity with the effect of initial chromium ions concentration, temperature and initial ...

Sorption techniques are widely used to remove heavy metal ions from large volumes of aqueous solutions. Herein, the natural and some artificial materials, such as clay minerals, biosorbents, carbon-nanomaterials, metal oxides, are reviewed as adsorbents in the removal of different heavy metal ions, such as Ni(II), Cu(II), Pb(II), Cd(II), Cs(I), Eu(III), Th(IV), Cr(VI) from large volumes of aque...

this paper discusses the biosorption of ni(ii) ions from aqueous solutions by bacillus sphaericus biomass. the biosorption process was affected by the solution ph, biomass concentration, contact time, temperature and initial ni(ii) concentration respectively. the sorption kinetics and equilibrium data were described well with the pseudo-second order kinetic model and the freundlich isotherm mod...

Arsenic, one of the most toxic and dangerous elements in the environment affecting millions of people around the world, is associated with several diseases. In this pilot study, we investigated removal of arsenate from aqueous solutions using chitosan under the influences of initial arsenic ion concentrations, pH, contact time, and adsorbent dosages of chitosan. In order to assess the sorption ...

In this article, the sorption process of Cr, As and V as oxoanions using modified mordenite zeolite as sorbent has been experimentally estimated. The sample of mordenite zeolite was synthesized and modified and batch method was employed for analysis. Parameters such as sorbent dose, concentration of metal oxoanions in solution ranging from 50 to 5 μg/l and effect of contact time were studied. E...

The sorption of a protein pair on carboxylic cation exchangers with various contents of ionogenic groups is examined. The bi-Langmuir isotherm calculation is carried out from sorption data for single-component systems. It is shown that good agreement of calculated and experimental data is reached only when protein-sorbent interaction weakens because of implementation of the competitive sorption...

The sorption of lead ion onto palm kernel fiber was studied by performing batch kinetic sorption experiments. The batch sorption model, based on a pseudo-second-order mechanism, was applied to predict the rate constant of sorption, the equilibrium capacity and the initial sorption rate with the effects of the initial solution pH and fiber dose. Equilibrium concentrations were evaluated with the...