separation of polycyclic aromatic hydrocarbons was performed by rp-hplc using mixed micellar mobile phase. effect of temperature, types and amounts of coorganic solvent in mobile phase on efficiency, asymmetry factor and selectivity factor showed that the appropriate condition for separation of these compounds was 3% isopropanol (v/v) as co-organic solvent in mobile phase at 40°c. analysis of t...

Separation of Polycyclic Aromatic Hydrocarbons was performed by RP-HPLC using mixed micellar mobile phase. Effect of temperature, types and amounts of coorganic solvent in mobile phase on efficiency, asymmetry factor and selectivity factor showed that the appropriate condition for separation of these compounds was 3% isopropanol (V/V) as co-organic solvent in mobile phase at 40°C. Analysis of...

Chemometric tools were used to generate the modelling of solvent effects on the N-alkylation of an isocyanuric acid salt. The method proceeded from a central composite design applied on the Carlson solvent classification using principal components analysis. The selectivity of the reaction was studied from the production of different substituted isocyanuric derivatives. Response graphs were obta...

The exacting selectivity of enzymatic catalysis is the most valuable characteristic of enzymes to the synthetic chemist. Ironically, this strict specificity also limits the generality of enzymatic synthesis, because enzymes that catalyze the reaction of interest with the desired selectivity are not always available. Nonaqueous enzymology, and the discovery that enzymatic selectivity can be chan...

Porous liquid zeo-PLs, a novel class of solvent, provide more efficient CO 2 separation from CH 4 and economical alternative over the current Genosorb solvent dissolution technology. Current technologies by solvents suffer either high regeneration costs or low selectivity/capacity solvent. Dispersing ca. 12.5 wt% -selective zeolite rho solid into commercial capture Genosorb® converts it porous ...

The presented study describes the solvent extraction process of Zn(II) and Pb(II) from aqueous solutions by a cation exchanger extractant named bis(2-ethylhexyl)phosphoric acid (DEHPA). The results confirm that both of the extraction efficiency and extraction selectivity depend on the employed organic diluent. The applied extractant was selective towards zinc ions; this selectivity did not depe...

a simple extremely fast and efficient approach for the synthesis of substituted indazole ingood to excellent yield catalyzed by using silica sulfuric acid (ssa) in dmso solvent at roomtemperature. this is solid state reaction have been attracting the synthetic organic chemist asthey provided enhance reaction rates, less environmental pollution, greater selectivity, cleanerproducts and manipulat...

Transforming lignocellulosic biomass into fuels and chemicals has been intensely studied in recent years. A large amount of work has been dedicated to finding suitable solvent systems, which can improve the transformation of biomass into value-added chemicals. These efforts have been undertaken based on numerous research results that have shown that organic solvents can improve both conversion ...