The tridentate ligands E(CH2CH2OPiPr2)2 (E = NH 1, E = S 2) were employed in the synthesis of a number of ruthenium complexes. Reaction of these ligands with (Ph3P)3RuCl2 afforded the dimers [Ru(HN(CH2CH2OPiPr2)2)Cl(μ-Cl)]2 (3) and [(Ru(E(CH2CH2OPiPr2)2))2(μ-Cl)3][X] (E = NH, X = PF64, E = S, X = Cl 5), respectively. Using (Ph3P)3RuHCl in reactions with 1 gave Ru(NH(CH2CH2OPiPr2)2)(PPh3)HCl (6)...

abu al-thana' shihab al-din mahmoud alusi baghdadiwas one of the quranic commentators of the 13th century, a follower of naghshbandiyyahsufi order, and the author of the quranic commentary, ruh al-ma'ani.  one of the importantaspects of his commentary is the approach of the author to the tradition of themystical commentary. alusi had the mystical tendencies, and in some placesreflecte...

Hydrogenation of the water-soluble [{RuCl(2)(mtppms)(2)}(2)] (mtppms = monosulfonated triphenylphosphine) was studied in aqueous solutions in the presence of excess mtppms both with H(2) and with aqueous HCOONa. Depending on the reductant, the pH and H(2) pressure altogether nine hydride species were identified. In acidic solutions at 1 bar H(2) pressure the known [RuHCl(mtppms)(3)] (1) and [{R...

Two hydrido ruthenium complexes could be isolated from the reaction between RuCl2(DMSO)4 (DMSO ) dimethyl sulfoxide) and the chelating 1,2-bis(dicyclohexylphosphino)ethane (dcpe) and [BPh4]. These are [RuH(dcpe)2][BPh4] with a five-coordinate, 16 valence electron cation and the neutral zwitterionic 18 valence electron compound {(η-C6H5)BPh3}RuH(dcpe). The relative amounts of these products depe...

The article deals with the life and work of Shihabuddin al-Alusi. In particular, al-Alusi, his creative path, teachers students, family, writings are described. addition, religious, political social situation in country where al-Alusi lived. Also main part this article, we see that is a mujtahid scholar who familiar controversial issues different sects follower Shafi school, but most cases he f...