stable crystalline phosphorus ylides are obtained in excellent yields from the 1:1:1 addition reactionbetween hydantoins or thiohydantoins and dialkyl acetylenedicarboxylates in the presence oftriphenylphosphine. these phosphoranes undergo smooth intramolecular wittig reaction followedby an electrocyclic ring opening to produce dialkyl (e)-2-(2,5-dihydro-5,5-diaryl-2-thioxo-1h-imidazol-4-yl)fum...

Rotational energy is widely distributed in many industrial and domestic applications, such as ventilation systems, moving vehicles and miniature turbines. This paper reports the design and implementation of a bi-stable rotational energy harvester with wide bandwidth and low operating frequency. The rotational energy is converted into electricity by magnetic plucking of a piezoelectric cantileve...

Solar magnetic tornadoes are known to be one of the mass and energy transport mechanisms from the lower solar atmosphere into the upper layers of the solar corona. A bright spiral structure with two arms is observed using high-cadence EUV images of 171, 193 and 304 Ǻ channels of Atmospheric Imaging Assembly (AIA) aboard the Solar Dynamics Observatory (SDO) on 10th of July 2011 for three hours. ...

We investigate the free cooling of inelastic rough spheres in the presence of Coulomb friction. Depending on the coefficients of normal restitution ǫ and Coulomb friction μ, we find qualitatively different asymptotic states. For nearly complete normal restitution (ǫ close to 1) and large μ, friction does not change the cooling properties qualitatively compared to a constant coefficient of tange...

Rotational energy is abundant and widely available in our living environment. Harvesting ambient rotational energy has attracted great attention. In this work, we report a single-electrode-based rotating triboelectric nanogenerator (SR-TENG) for converting rotational energy into electric energy. The unique advantage of introducing the single-electrode TENG is to overcome the difficulty in makin...

We investigate theoretically the rotational dynamics of pyramidal XY3 molecules in highly excited rotational states. Towards this end we compute, by a variational method, the rotational energy levels in the vibrational ground state of PH3 for J < or = 80. At J > or = 50 the calculated energy levels show a distinct cluster pattern. By monitoring the cluster formation we follow the various stages...

Stable crystalline phosphorus ylides are obtained in excellent yields from the 1:1:1 addition reactionbetween hydantoins or thiohydantoins and dialkyl acetylenedicarboxylates in the presence oftriphenylphosphine. These phosphoranes undergo smooth intramolecular Wittig reaction followedby an electrocyclic ring opening to produce dialkyl (E)-2-(2,5-dihydro-5,5-diaryl-2-thioxo-1H-imidazol-4-yl)fum...

The IBr fragment rotational state distributions that result when the NeIBr van der Waals molecule undergoes vibrational predissociation have been measured in a pump-probe laser-induced fluorescence experiment. Independent of initial vibrational state and the number of quanta of vibrational energy lost from the I-Br coordinate, the rotational distributions extend over the full range of energetic...