Equatorial/axial conversion in piperidine and phosphorinane with different substituents wereinvestigated with great details. Three possible routes, i.e. heteroatom inversion and two ring inversiontype were considered. Ring conversion can occur via two pathways one starts with ring flatteningfrom the heteroatom site (nitrogen in piperidine and phosphorous in phosphorinane) and the otherinitiates...

equatorial/axial conversion in piperidine and phosphorinane with different substituents wereinvestigated with great details. three possible routes, i.e. heteroatom inversion and two ring inversiontype were considered. ring conversion can occur via two pathways one starts with ring flatteningfrom the heteroatom site (nitrogen in piperidine and phosphorous in phosphorinane) and the otherinitiates...

a method is described by which it is possible to determine the high barrier to ring inversion and hindered rotation by neat racemization of optically active compounds when the racemization is caused by ring inversion or hindered rotation. the method is based preparation of sufficiently pure enantiomers, mainly by chromatography on swollen microcrystalline triacetylcellulose (tac). by this techn...

A method is described by which it is possible to determine the high barrier to ring inversion and hindered rotation by neat racemization of optically active compounds when the racemization is caused by ring inversion or hindered rotation. The method is based preparation of sufficiently pure enantiomers, mainly by chromatography on swollen microcrystalline triacetylcellulose (TAC). By this t...

For any reduced commutative $f$-ring with identity and bounded inversion, we show that a condition which is obviously necessary for the socle of the ring to coincide with the socle of its bounded part, is actually also sufficient. The condition is that every minimal ideal of the ring consist entirely of bounded elements. It is not too stringent, and is satisfied, for instance, by rings of ...

for any reduced commutative $f$-ring with identity and bounded inversion, we show that a condition which is obviously necessary for the socle of the ring to coincide with the socle of its bounded part, is actually also sufficient. the condition is that every minimal ideal of the ring consist entirely of bounded elements. it is not too stringent, and is satisfied, for instance, by rings of conti...

conformational properties of n-aryl-1-azacyclooctan-5- ones with a p-methyl, m-methyl, and p-methoxy group as a substituent have been studied by 1h-nmr, 13c-nmr and ir spectroscopies. transannular interaction of the two functional groups have been examined from the ring inversion barriers and the carbonyl vibrational frequencies with reference to the corresponding data of the respective monofun...

Conformational properties of N-aryl-1-azacyclooctan-5- ones with a p-methyl, m-methyl, and p-methoxy group as a substituent have been studied by 1H-NMR, 13C-NMR and IR spectroscopies. Transannular interaction of the two functional groups have been examined from the ring inversion barriers and the carbonyl vibrational frequencies with reference to the corresponding data...