2-amino-substituted ketones react with α-methylene ketones under solvent-free conditions at 90 °c in thepresence of a catalytic amount of zirconium dodecylphosphonate to create the corresponding quinolinesin excellent yields. this procedure recommends numerous advantages such as easy work-up, use of mild,reusable and safe catalyst, short reaction timeand high yields. the new compounds have been...

zrp2o7 nanoparticles have been used as an efficient catalyst for the preparation of 2-aryl-5-methyl-2,3-dihydro-1h-3-pyrazolones by a simple one-pot four-component reaction of phenyl hydrazines, ethyl acetoacetate ,β-naphthol and benzaldehydes under microwave irradiation in good to excellent yields. when the reaction was carried out using zrocl2.8h2o, zro2 and zrp2o7 nps as the catalyst, the pr...

the ionic liquid li(ohch2ch2nh2)(cf3oac) was found to efficiently catalyze the three-component reaction between different enols, aldehydes, and malononitrile , leading to rapid synthesis of 2-amino-4h-chromene derivatives in fairly high yields. the catalyst is easily prepared, highly stable, simple to handle and recycled for several times without significant loss of activity. the method is simp...

the brønsted acidic ionic liquid ([bmim]hso4) catalyzed three-component synthesis of 2h-indazolo[2,1-b]phthalazine-trione derivatives at room temperature. the integrity of the ionic liquid remains reasonably unchanged when it is separated from the reaction mixture by water extraction, as it can be recycled several times without any loss of activity in each of the title syntheses. the products a...

dodecylbenzenesulfonic acid (dbsa) was used as an efficient, cheap and stable brønsted catalyst for acetylation of alcohols and phenols and formylation of alcohols under solvent-free conditions. various primary, secondary and tertiary alcohols were acetylated with acetic anhydride as an acetylating agent under solvent-free conditions in the presence of catalytic amount of dbsa at room temperatu...

1,2-diketones have been reacted in one-pot method with 1,2-diamines at room temperature with zno nanoparticles as a catalyst. zno nanoparticles as an available and reusable catalyst is used for the synthesis of quinoxalinein improved yields.

cobalt hydrogensulfate is an efficient catalyst for the condensation of β-naphthol, aromatic aldehydes and 5,5-dimethyl-1,3-cyclohexanedione at 120 °c to afford 9,9-dimethyl-12-phenyl-8,10,11,12-tetrahydro-9-h-benzo[a]xanthen-11-one derivatives in high yields. also, polycondensation reactions of phenols with phthalic anhydride were carried out in the presence of cobalt hydrogensulphate under so...

a green, efficient and selective approach for the oxidation of sulfides to sulfoxides and sulfones with uhp at room temperature is reported. the reaction is performed in the presence of vanadia catalyst supported on mesocellular silica foam (mcf) with a v content ranging from 2% to 10% as heterogeneous and reusable catalyst. the structural and textural characterization of this catalyst were don...

1,2-Diketones have been reacted in one-pot method with 1,2-diamines at room temperature with ZnO nanoparticles as a catalyst. ZnO nanoparticles as an available and reusable catalyst is used for the synthesis of Quinoxalinein improved yields.