Surface carbonate sediments from sites on the Bahamas Bank with different seagrass densities were incubated across a range of O2 delivery rates, to study the controls on metabolic carbonate dissolution in these sediments. The results confirmed the 1:1 ratio between the rates of O2 consumption and carbonate dissolution, demonstrating that microbial respiration was the ratelimiting step in metabo...

Using two complimentary approaches (pore water advection/diffusion/ reaction modeling and stable isotope mass balance calculations) we show that carbonate dissolution/reprecipitation occurs on early diagenetic time scales across a broad range of sediments on the Great Bahamas Bank. The input of oxygen into the sediments, which strongly controls sediment carbonate dissolution, has two major sour...

Nanoparticles of a novel organic zwitterionic Meisenheimer complex, N',N' ',N' ''-tri(isopropyl)-4-oxo-6-(isopropyliminio)-2-s-(2H)triazinespiro-1'-2',4',6'-trinitrocyclohexadienylide, were synthesized by reprecipitation in water under different conditions. While reprecipitation alone resulted in a suspension of amorphous particles that fell out of solution within hours, sonication for differen...

Water-dispersed organic nanoparticles (NPs) constructed by the conjugated molecule 2,5,2',5'-tetra(4'-N,N-diphenylaminostyryl)biphenyl (DPA-TSB) with a high luminescence and large two-photon absorption (TPA) section were fabricated via the reprecipitation method. The average size of the NPs can be controlled from 40 nm to 80 nm by adjusting the reprecipitation conditions. The NPs in water dispe...

The authors demonstrate a smart and versatile approach for preparing multi-spectral conjugated polymers from a commercial precursor MEH-PPV without tedious synthetic modification. Multi-color CPNs with small size have also been successfully prepared using a modified-reprecipitation procedure for live cell imaging.

Nanocrystals of several oligosilanes have been fabricated easily by using a reprecipitation method. The nanocrystals reveal an intense absorption band at the UVB region (280 to 320 nm) and a fluorescence band with large Stokes shift. These photophysical properties show that the nanocrystals exhibit an excitonic interaction of the H-aggregate type.