نتایج جستجو برای: recoverable catalyst
تعداد نتایج: 46271 فیلتر نتایج به سال:
a novel acrylic acid-functionalized fe3o4 magnetic nanoparticle with a core-shell structure was developed for utilization as a heterogeneous organosuperacid in chemical transformations. the structural, surface, and magnetic characteristics of the nanosized catalyst were investigated by various techniques such as transmission electron microscopy (tem), thermogravimetric analysis (tga), and ft-ir...
n-propylsulfamic acid supported onto magnetic fe3o4 nanoparticles (mnps-psa) was investigated as an efficient and magnetically recoverable catalyst for the one-pot synthesis of substituted coumarins from the reaction of coumarin with variety aromatic aldehydes in high to excellent yield at room temperature under solvent-free conditions. the magnetic nanocatalyst can be readily recovered easily ...
Deprotection of various phenols from their respective methoxymethyl ethers using an heteropolyacid catalyst was studied. The catalyst was the Wells-Dawson heteropolyacid, used both in bulk or supported on silica. Yields were high to quantitative after less than one hour reaction time and the catalyst was easily recoverable and reusable.
Attempts are made to define the “ideal synthesis”, “ideal catalyst”, and “ideal recoverable catalyst”. Although these unattainable limits can never be realized, they help to focus attention on attributes chemists should strive for. Criteria for evaluating catalyst recovery are analyzed, and increased attention to the critical and constructive evaluation of competing “green” chemical technologie...
A magnetically recoverable catalyst consisting of Mn (III) salophen complex was prepared. The synthesized catalyst was characterized by X-ray powder diffraction (XRD), transmission electron microscopy (TEM), vibrating sample magnetometry (VSM), inductively coupled plasma atomic emission spectroscopy (ICP-AES) and Fourier transform infrared (FT-IR). The immobilized catalyst was shown to be an ef...
in the current study, a magnetic inorganic–organic nanohybrid material (hpa/tpi-fe3o4) was produced and used as an efficient, highly recyclable and eco-friendly catalyst for the one-pot and multicomponent synthesis of 3,4-dihydroquinoxalin-2-amine, diazepine-tetrazole and benzodiazepine-2-carboxamide derivatives with high yields and in a short range of time (20–35 min). the nanohybrid catalyst ...
The 5-alkylthio and 5-arylthiotetrazoles were efficiently synthesized from thiocyanates using Fe3O4 nanoparticles as a magnetically recoverable and reusable catalyst. The main advantages allocated to this method are elimination of hydrazoic acid as a dangerous and harmful reagent, high yields and ease of product isolation. The catalyst can be simply recovered by an external magnet and reused wi...
A simple and efficient synthetic protocol has been developed for the synthesis of 3-substituted-2H-1,4-benzothiazines by using a novel sulfonic acid functionalized nano-γ-Al2O3 catalyst, devoid of corrosive acidic, and basic reagents. The developed method has the advantages of good to excellent yields, short reaction times, operational simplicity, and a recyclable catalyst. The catalyst can be ...
A magnetically recoverable catalyst consisting of Mn (III) salophen complex was prepared. The synthesized catalyst was characterized by X-ray powder diffraction (XRD), transmission electron microscopy (TEM), vibrating sample magnetometry (VSM), inductively coupled plasma atomic emission spectroscopy (ICP-AES) and Fourier transform infrared (FT-IR). The immobilized catalyst was shown to be an ef...
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