in this study, the stability of trinitroglycerin (tng) in polyethylene (peg) 400 was investigated according to arrhenius approach. the reaction rate constant (k) for the thermal disintegration of tng in peg 400 at various temperatures was counted based on the percents of remaining tng at different intervals of time at a specific temperature. the results showed that “k” at 40, 50, 60, 70, 80 and...

the kinetics and mechanism of the reaction of 5-nitro-1h-benzo[d] imidazole to produce 6-nitro-1h-benzo[d] imidazole was studied by employing hybrid meta-density functional theory. mpwblk/6-31+g** level calculations were carried out to obtain energies and optimize the geometries of all stationary points along the pes, and determine the harmonic vibrational frequencies. two transition states (ts...

application of phosphorus (p) fertilizers as solid or liquid fertilizers to soils leads to re-actions of orthophosphate ions with various soil components which remove p from the so-lution phase and convert it to less soluble phosphates. this study was aimed at determin-ing soil properties that affect the rate of phosphate retention in 28 contrasting calcareous soils from different geographical ...

2006;571;502-; originally published online Feb 2, 2006; J. Physiol. Stephen W. Jones Are rate constants constant? This information is current as of March 21, 2006 publication unless article is open access. This version of the article may not be posted on a public website for 12 months after http://jp.physoc.org/cgi/content/full/571/3/502 This is the final published version of this article; it i...

on the basis of experimental data a kinetic model for the heterogeneous interaction between alkylperoxyradicals and organic compounds in langmuir- hinshelwood approach at room temperature has been offered.the effect of oxygen on the kinetics of process in the presence, [o2]o = 1 x 1011 – 1.6 x 1012 molecules.cm-2, and absence of oxygen has been analyzed. over time the chain degenerate branching...