Immobilized TiO2 nanotube arrays (NTAs) co-modified with Pt and CdS nanoparticles were fabricated by using the combination of photoreduction and chemical bath deposition methods. XRD, SEM, TEM, XPS, UV-Vis and EDX methods were employed to characterize the microstructure and composition of samples, and the results showed that CdS and Pt NPs were uniformly deposited on the surface of TiO2 nanotub...

Conventional supported Pt catalysts have often been prepared by loading Pt onto commercial supports, such as SiO2, TiO2, Al2O3, and carbon. These catalysts usually have simple metal-support (i.e., Pt-SiO2) interfaces. To tune the catalytic performance of supported Pt catalysts, it is desirable to modify the metal-support interfaces by incorporating an oxide additive into the catalyst formula. H...

Absorption spectra (150-300 nm) of TiO2 and TiO2 modified with metal (Pt, Pd, and Au) nanoparticles were systematically measured using an attenuated total reflection-far ultraviolet spectrometer. The deposition of metal nanoparticles altered the spectral shape and intensity, indicating changes in the electronic states and photocatalytic activities of TiO2.

Platinum-ion-doped TiO2 (Pt(ion)-TiO2) was synthesized by a sol-gel method, and its visible light photocatalytic activities were successfully demonstrated for the oxidative and reductive degradation of chlorinated organic compounds. Pt(ion)-TiO2 exhibited a yellow-brown color, and its band gap was lower than that of undoped TiO2 by about 0.2 eV. The flat band potential of Pt(ion)-TiO2 was posit...

Pt@TiO2@CNTs hierarchical structures were prepared by first functionalizing carbon nanotubes (CNTs) with nitric acid at 140 °C. Coating of TiO2 particles on the CNTs at 300 °C was then conducted by atomic layer deposition (ALD). After the TiO2@CNTs structure was fabricated, Pt particles were deposited on the TiO2 surface as co-catalyst by plasma-enhanced ALD. The saturated deposition rates of T...

A novel hierarchical Pt- and FTO-free counter electrode (CE) for the dye-sensitized solar cell (DSSC) was prepared by spin coating the mixture of TiO2 nanoparticles and poly(3,4-ethylenedioxy-thiophene):poly(styrenesulfonate) (PEDOT:PSS) solution onto the glass substrate. Compared with traditional Pt/FTO CE, the cost of the new CE is dramatically reduced by the application of bilayer TiO2-PEDOT...

This study explores a facile method to prepare an efficient and durable support for Pt catalyst of polymer electrolyte membrane fuel cell (PEMFC). As a candidate, Nb-doped TiO2 (Nb-TiO2) nanofibers are simply fabricated using an electrospinning technique, followed by a heat treatment. Doping Nb into the TiO2 nanofibers leads to a drastic increase in electrical conductivity with doping level of ...

Nanoporous Pt/TiO2 micro-particles were synthesized via an aerosol assisted co-assembly (AACA) route. Aerosol droplets were produced from a colloidal mixture of 5 nm Pt and 20 nm TiO2 nanoparticles, which formed spherical micro-aggregates of Pt and TiO2 with average diameter of around 1.2 μm. The resulting composite micro-particles have very open structure with pore sizes ranging from 20 to 200...

A variety of combinations of CdS, TiO2, and Pt in preparing the hybrid catalysts were studied for hydrogen production under visible light (l > 420 nm) irradiation. The preparation method sensitively influenced the activity of the ternary hybrid catalysts. The formation of the potential gradient at the interface between CdS and TiO2 is necessary in achieving the efficient charge separation and t...

A novel electrochemical sensor poly(taurine)/TiO2-graphene nanocomposite modified glassy carbon electrode (PT/TiO2-Gr/GCE) was fabricated. This sensor was based on an electrochemically polymerized taurine layer on a TiO2-graphene modified glassy carbon electrode. The electrochemical behavior of acetaminophen and caffeine at the modified electrode was studied by cyclic voltammetry and differenti...