bis(indenyl)zirconium dichloride as a catalyst was synthesized using a modified method at the room temperature. polymerization of ethylene and copolymerization of ethylene and propylene were carried out by this metallocene catalyst. ethylene propylene (p/e) feed ratios of 0.25, 0.5, 1, and 2 were employed into the copolymerization systems. copolymerization conditions like cocatalyst/catalyst ra...

epoxy – polysulfide copolymers without or with low amounts of epoxy in their structure have poor mechanical properties in oxidative curing system.to strengthen the mechanical properties of polysulfide elastomer inclusion of epoxy resin (epon828) as hard segment was studied. ft-ir spectroscopy and rheometry were used to verify the formation of epoxy-polysulfide copolymer.  results obtained from ...

Poly(m-chloroaniline) (3clp), polydiphenylamine (dpa), copolymer of diphenylamine and mchloroaniline (3clpdpa), composite of copolymer with TiO2 (3clpdpat), and composite of copolymer with ZnO (3clpdpaz) have been chemically prepared by oxidative polymerization of polymer and copolymer with TiO2, ZnO. These were characterized by FTIR, UV–visible, Fluorescence spectra, Atomic force microscopy an...

Epoxy – Polysulfide copolymers without or with low amounts of epoxy in their structure have poor mechanical properties in oxidative curing system.To strengthen the mechanical properties of polysulfide elastomer inclusion of epoxy resin (Epon828) as hard segment was studied. FT-IR spectroscopy and rheometry were used to verify the formation of epoxy-polysulfide copolymer.  Results obtained f...

Objective(s) Physiological changes in the body may be utilized as potential triggers for controlled drug delivery. Based on these mechanisms, stimulus-responsive drug delivery has been developed. Materials and Methods In this study, a kind of poly (N-isopropylacrylamide-acrylamide) membrane was prepared by radical copolymerization. Changes in swelling ratios and diameters of the membrane wer...

The thermal decomposition of 86 % vinyl chloride 14 % vinyl acetate copolymer wasstudied by the conductometry technique in the presence of nitrogen. The kinetics of stability andthermal degradation of vinyl chloride- co- vinyl acetate (PVC- co- PVAc) copolymer withcopper, copper oxide and tricalcium dicitrate (st) were investigated at various temperatures (150-180 oC ) in solution. The rate coe...

the thermal decomposition of 86 % vinyl chloride 14 % vinyl acetate copolymer wasstudied by the conductometry technique in the presence of nitrogen. the kinetics of stability andthermal degradation of vinyl chloride- co- vinyl acetate (pvc- co- pvac) copolymer withcopper, copper oxide and tricalcium dicitrate (st) were investigated at various temperatures (150-180 oc ) in solution. the rate coe...

To obtain one biodegradable and electroactive polymer as the scaffold for tissue engineering, the multiblock copolymer PLAAP was designed and synthesized with the condensation polymerization of hydroxyl-capped poly( l-lactide) (PLA) and carboxyl-capped aniline pentamer (AP). The PLAAP copolymer exhibited excellent electroactivity, solubility, and biodegradability. At the same time, as one scaff...

Incorporation of a block copolymer into a thin polymer film is observed to alter both the rate and mechanism by which the film dewets from an immiscible polymer substrate. Films with little or no copolymer dewet by classical nucleation and growth of circular holes, and the dewetting rate decreases with increasing copolymer concentration. Increasing the copolymer content at constant film thickne...