kinetic parameters of the ammonolysis reaction of dichloroethane in nonaqueous media are studied and the optimum reaction conditions are reported. a suitable reactor for running the reaction under high pressure in the range of 50 to 500 °c is designed. kinetic behaviours of the system is studied and other reaction parameters such as rate constant, kinetic order, and activation energy are determ...

Kinetic parameters of the ammonolysis reaction of dichloroethane in nonaqueous media are studied and the optimum reaction conditions are reported. A suitable reactor for running the reaction under high pressure in the range of 50 to 500 °C is designed. Kinetic behaviours of the system is studied and other reaction parameters such as rate constant, kinetic order, and activation energy are de...

A novel approach for preparation of ultra-bright fluorescent nanodiamonds (fNDs) was developed and the thermal and kinetic optimum of NV center formation was identified. Combined with a new oxidation method, this approach enabled preparation of particles that were roughly one order of magnitude brighter than particles prepared with commonly used procedures.

The kinetic resolution of racemic material is a well-established approach used to prepare a wide range of enantiomerically enriched compounds. However, the overall efficiency of a standard kinetic resolution is limited to a maximum theoretical yield of 50% of the enriched chiron, with the balance of undesired material being discarded in most applications. As a result of this inherent overall ef...

AIM The objectives of this study were to assess the influence of four different kinetic cavity preparation devices on cavity preparation taking into account tip angulation, internal tip diameter, and distance to the dental substrate. The dental topography itself was also evaluated after the use of these devices. METHODS AND MATERIALS Quantitative parameters using pertinent statistical tests a...