Straining of PVA/PE and PVA/PP blends (70:30) is monitored by small-angle x-ray scattering (SAXS). Sheet-extruded films with different predraw ratio are investigated. The discrete SAXS of predrawn samples originates from polyolefin nanofibrils inside of polyolefin microfibrils immersed in a PVA matrix. PE nanofibrils deform less than the macroscopic strain without volume change. PP nanofibrils ...

This mini-review article addresses the development in synthesizing polyolefin/clay nanocomposites by olefin polymerization under catalysis of clay intercalated precatalysts in recent years. The review comprises three parts which focus on mainly the synthetic route, structural characterization, and properties of polyolefin/clay nanocomposites, respectively. Moreover, outlook for future research ...

A method has been developed for the quantitative determination of the composition of thermoplastic wood composites. The method involves area measurements of the two peaks in the derivative curve of a tracing produced by the thermogravimetric analysis (TGA) of a thermoplastic composites sample in an inert atmosphere. This may involve the standard, constant heating rate-method, or the high resolu...

Polyolefin, as one of the most widely used macromolecule materials, has been one of the most serious threats to the environment. Current treatment methods of waste polyolefin including landfill, incineration, and thermal degradation have suffered from severe problems such as secondary pollution and the generation of other toxic substances. In this article, we report for the first time a high-ef...

This paper discusses two common problems, “weld tenting” and low coating thickness over the external weld, and their causes in traditional three layer polyolefin pipeline coatings. To tackle these problems, a new approach to applying multilayer polyolefin coating to pipes is introduced. The new system consists of side-extruding high density polyethylene over a graded structure polyethylene (GSP...

Along with greatly shaking up the confidence in producers and distributors, the problems, such as BSE and avian influenza, which are threatening the safety of agricultural products occurring one after another, have suddenly increased our the awareness of “food safety” as consumers. On the other hand, even though Japanese agriculture is facing internal and external problems such as the depressio...

Transition-metal catalysts long ago made it from the laboratory bench to the polymerization reactor. Indeed, they are being used around the world to make more than 70 million tons of polyethylene and polypropylene a year. Transition-metal catalysts give polyolefin producers unprecedented flexibility in process and polymer design. However, there are still new worlds for catalysts to conquer. One...

Research on "post-metallocene" polymerization catalysis ranges methodologically from fundamental mechanistic studies of polymerization reactions over catalyst design to material properties of the polyolefins prepared. A common goal of these studies is the creation of practically useful new polyolefin materials or polymerization processes. This Review gives a comprehensive overview of post-metal...