long-chain diacrylate crosslinkers based on linear α,ω-diols were synthesized and characterized using ftir and 1h nmr spectroscopy. the highest reaction yield (99.5%) was due to polyethylene glycol diacrylate 1000 (pegda-1000). then, kaolin-containing poly(potassium acrylate-acrylic acid) superabsorbent composites and kaolin-free counterparts were synthesized using pegda-1000.the effect of the ...

OBJECTIVE To investigate cross-linked hydrogels prepared via inverse emulsion polymerization to entrap poorly aqueous soluble drugs. Polyethylene glycol cross-linked acrylic polymers were synthesized and the loading and release of curcumin, a model hydrophobic drug, was investigated. METHODS Physicochemical characteristics of hydrogels were studied with (13)C nuclear magnetic resonance, Fouri...

We report the preparation of polyglycerol particles on different length scales by extending the size of hyperbranched polyglycerols (3 nm) to nanogels (32 nm) and microgels (140 and 220 μm). We use miniemulsion templating for the preparation of nanogels and microfluidic templating for the preparation of microgels, which we obtain through a free-radical polymerization of hyperbranched polyglycer...

Engineering complex extracellular matrix (ECM) is an important challenge for cell and tissue engineering applications as well as for understanding fundamental cell biology. We developed the methodology for fabrication of precisely controllable multiscale hierarchical structures using capillary force lithography in combination with original wrinkling technique for the generation of well-defined ...

Polydimethylsiloxane (PDMS), commonly used in microfluidics, is susceptible to nonspecific adsorption of molecules and biological analytes, such as proteins. PDMS requires coating or chemical modification to overcome this problem. We optimized a single-monomer formulation of polyethylene glycol diacrylate (PEGDA), which upon polymerization to form polyPEGDA, provides reduced susceptibility to n...

cross-linked polymeric organogels have attracted much attention in recent years. most synthesized organogels are based on low molecular weight or denderitic materials. the study focuses on the preparation of an alcohol absorbent organogel based on 2-acrylamido-2-methylpropane sulphonic acid (amps) through cross-linking polymerization. polyethylene glycol diacrylate-400 and ammonium persulphate ...