beside ziegler-natta and phillips catalysts the development of methylaluminoxane (mao) as cocatalyst incombination with metallocenes or other transition metal complexes for the polymerization of olefins haswidely increased the possibilities in controlling the polymer composition, polymer structure, tacticity and special properties with high precision. these catalysts allow the synthesis of isot...

For the purpose of increasing the permeability to oxygen and equilibrium water content in contact lenses, polar copolymers with nonionic monomers such as 2-hydroxyethle methacrylate(HEMA) Is used. By adding the polar monomers to (HEMA), the permeability to oxygen and equilibrium with water content is increased and also the absorption of proteins on lens surface is changed. In this research, the...

for the purpose of increasing the permeability to oxygen and equilibrium water content in contact lenses, polar copolymers with nonionic monomers such as 2-hydroxyethle methacrylate(hema) is used. by adding the polar monomers to (hema), the permeability to oxygen and equilibrium with water content is increased and also the absorption of proteins on lens surface is changed. in this research, the...

Beside Ziegler-Natta and Phillips catalysts the development of methylaluminoxane (MAO) as cocatalyst in combination with metallocenes or other transition metal complexes for the polymerization of olefins has widely increased the possibilities in controlling the polymer composition, polymer structure, tacticity and special properties with high precision. These catalysts allow the synthesis of is...

We have been engaged in a search for coordination catalysts for the copolymerization of polar monomers (such as vinyl chloride and vinyl acetate) with ethylene. We have been investigating complexes of late transition metals with heterocyclic ligands. In this report we describe the synthesis of a symmetrical bis-thiadiazole. We have characterized one of the intermediates using single crystal X-r...

measuring the rate of changes in total polar compounds (tpc) content and polar fractions, the oxidative stability of canola oil during frying process as affected by bene kernel oil (bko, 0.05 and 0.1%) and tert-butylhydroquinone (tbhq, 100ppm) was investigated. it was observed that the tpc content increased linearly with frying time (r2 > 0.98). the canola oil containing the bko (especially 0.1...

We investigate the properties of a two-dimensional lattice heteropolymer model for a protein in which water is explicitly represented. The model protein distinguishes between hydrophobic and polar monomers through the effect of the hydrophobic monomers on the entropy and enthalpy of the hydrogen bonding of solvation shell water molecules. As experimentally observed, model heteropolymer sequence...

Folding channels and free-energy landscapes of hydrophobic-polar heteropolymers are discussed on the basis of a minimalistic off-lattice coarse-grained model. We investigate how rearrangements of hydrophobic and polar monomers in a heteropolymer sequence lead to completely different folding behaviors. Studying three exemplified sequences with the same content of hydrophobic and polar residues, ...