in the present work, a modified correlation is presented for the second virial coefficients of both polar and nonpolar fluids based on the corresponding states principle. the second virial coefficients of gaseous polar and non-polar compounds were calculated and compared with experimental data and with other correlations. comparisons with the existing correlations show that the present work is ...

In the present work, a modified correlation is presented for the second virial coefficients of both polar and nonpolar fluids based on the corresponding states principle. The second virial coefficients of gaseous polar and non-polar compounds were calculated and compared with experimental data and with other correlations. Comparisons with the existing correlations show that the present work is ...

frying oils showed an increase in peroxide value (pv) at the initial stages of the frying process followed by a decrease, and there was no correlation between pv and total polar compounds (tpc) in the same set of frying oils. all the frying oils had pvs lower than 4.42 meq o2 kg-1 oil during the frying process and, consequently, none of them was above the limit of 10 meq o2 kg-1 oil for edible ...

The extraction method is critical for the recovery of phenolic compounds. The main goal was to evaluate the effect of an extraction process from mango seed on their phenolic profile, antioxidant and antimicrobial capacities. Phenolic extraction was performed in different steps: maceration, alkaline hydrolysis, acid/alkaline hydrolysis, polar and non-polar fraction of an ethyl acetate separation...

Please direct correpsondence to Joseph Pesek at [email protected]. Separation and retention of both polar and nonpolar compounds by the same stationary phase can be a useful approach for analyses of complex samples with a broad range of chemical properties. Typical stationary phases are designed for retention of either polar or nonpolar compounds so that multiple steps are required when designing ...

The quest for solid-state materials with tailored chemical and physical features stimulates the search for general prescriptions to recognize and forecast their electronic structures providing valuable information about the experimentally determined bulk properties at the atomic scale. Although the concepts first introduced by Zintl and Hume–Rothery help to understand and forecast the bonding m...

Plant extracts may contain highly polar and/or highly non-polar substances which can interfere with the separation of pure compounds during isolation if they are present in a very high concentration. Commonly known examples of polar substances are carbohydrates, glycosides and amino acids, while non-polar substances include waxes, oils, sterols and chlorophylls (Klejdus et al. 1999). Preliminar...

Hydrophilic interaction chromatography (HILIC) was developed by Andrew Alpert for separation of highly polar compounds. HILIC is characterized by a high organic mobile phase concentration and the hydrophilic stationary phase. Thus, the retention times of highly polar compounds are increased with the increase of the hydrophilicity of the solutes. Recently, it became necessary to determine highly...