in this paper, labo3 perovskite type catalyst formulations were prepared by sol-gel auto combustion method using citric acid as the fuel. activity of catalysts was tested in catalytic oxidation of toluene as a model of volatile organic compounds. lacoo3 perovskite formulation showed the highest activity among labo3 (fe, mn and co) perovskite catalysts. so, lacoo3 perovskite based catalyst was s...

In this paper, LaBO3 perovskite type catalyst formulations were prepared by sol-gel auto combustion method using citric acid as the fuel. Activity of catalysts was tested in catalytic oxidation of toluene as a model of volatile organic compounds. LaCoO3 perovskite formulation showed the highest activity among LaBO3 (Fe, Mn and Co) perovskite catalysts. So, LaCoO3 perovskite based catalyst was s...

the perovskite-type oxides strontium-substituted lanthanum nickelate (lsno) were prepared by a coprecipitation method in the present of octanoic acid as surfactant. the phase composition, morphology,lattice parameters and size of nanoparticles in these materials were characterized through fourier transform infrared spectroscopy (ft-ir), x-ray diffraction (xrd), scanning electron microscopy (sem...

In this paper, catalytic oxidation of CO over the LaFe1-xCuxO3 (x= 0, 0.2, 0.4, 0.6) perovskite-type oxides was investigated. The catalysts were synthesized by sol-gel method and characterized by XRD, BET, FT-IR, H2-TPR and SEM methods. The catalytic activity of catalysts was tested in catalytic oxidation of CO. XRD patterns confirmed the synthesized perovskites to be single-phase perovskite-ty...

On the basis of the bond-valence model (BVM) and structure-map technology, the structural stability and formability of ABO(3)-type perovskite compounds were investigated in 376 ABO(3)-type compounds. A new criterion of structural stability for ABO(3)-type perovskite compounds has been established by the bond-valence calculated tolerance factors, which are in the range 0.822-1.139. All global in...

We found that two lithium niobate-type oxides, CdPbO3 and PbNiO3 were synthesized by high-pressure as metastable low-pressure perovskite-type phases. We then discussed the stability of lithium niobate-type and perovskite-type oxides relative to oxides with other structure for ABO3 compounds. Consequently, the tolerance factor of perovskite is not the only predominant one to determine the stabil...

The sequence of replacement in groundmass perovskite and spinel from SK-1 and SK-2 kimberlites (Eastern Dharwar craton, India) has been established. Two types of perovskite occur in the studied Indian kimberlites. Type 1 perovskite is found in the groundmass, crystallized directly from the kimberlite magma, it is light rare-earth elements (LREE)-rich and Fe-poor and its ∆NNO calculated value is...

In this work La0.7Sr0.3MnO3 , one group of nanosized perovskite-type oxides were prepared by sol-gel method. The perovskite structure has been characterized by X-ray diffraction (XRD) , scanning electron microscopy (SEM) , energy dispersive X-ray spectrometer (EDX) and Fourier transform infrared (FTIR) . The nanoparticles showed the excellent adsorption properties towards reactive blue 4 (RB4) ...

The purpose of this chapter is to understand the ionic conduction of perovskite-type oxides. It is based on the fundamental theories of perovskite structure, ionic conductivity, conductivity measurement, X-ray diffraction and Rietveld analysis, and nuclear magnetic resonance (NMR). Typical examples of lithium ionic conductor are introduced. Introduction Perovskite-type oxides have been consider...

In this article, we present a new paradigm for organometallic hybrid perovskite solar cell using NiO inorganic metal oxide nanocrystalline as p-type electrode material and realized the first mesoscopic NiO/perovskite/[6,6]-phenyl C61-butyric acid methyl ester (PC61BM) heterojunction photovoltaic device. The photo-induced transient absorption spectroscopy results verified that the architecture i...