نتایج جستجو برای: oxidation reaction
تعداد نتایج: 512047 فیلتر نتایج به سال:
in this study, a simple, rapid and selective method was developed for the determination of dexamethasone. the proposed method is based on inhibitory effect of dexamethasone on the oxidation of orange-g by bromate in sulfuric acid media. the reaction was followed spectrophotometrically at 478.5 nm (?max). under optimum experimental conditions, (72.6 ?mol l-1 of orange-g, 0.76 mol l-1 of h2so4, 0...
the reaction of ch₃nh₂ with o₂ on the singlet potential energy surfaces (pes) was carried out using the b3lyp, ccsd(t) and g3b3 theoretical approaches along with 6-311++g(3df,3pd) basis set. the suggested mechanism for the title reaction consists of one pre-reactive complex. from the pre-reactive complex, nine types of products, ch2nh+h2o2, ch3nh+ooh, nh2cho+h2o, ch2nho+h2o, nh3+hcooh, ch2nh+h2...
abstract part one: the electrode oxidation potentials of a series of eighteen n-hydroxy compounds in aqueous solution were calculated based on a proper thermodynamic cycle. the dft method at the level of b3lyp-6-31g(d,p) was used to calculate the gas-phase free energy differences ,and the polarizable continuum model (pcm) was applied to describe the solvent and its interaction with n-hydroxy ...
the catalytic oxidation of toluene to benzoic acid in the liquid phase has been studied in an un-stirred tank reactor. low concentration of acetic acid was added in order to increase the solubility of the catalyst in toluene. the dependence of the rate of reaction on the concentration of toluene catalyst and oxygen pressure was studied. it has been suggested that liquid phase oxidation of tolue...
In this article, the catalytic activity of bis[2-(p-tolyliminomethyl)phenolato] copper(II) complex was studied, for the first time, in the oxidation of various primary and secondary alcohols to the corresponding aldehydes or ketones. The effect of different solvent was studied in the oxidation of benzyl alcohol and methanol was chosen as the reaction medium. Also the effect of different oxidant...
چکیده ندارد.
The total oxidation of toluene at a wide temperature range (200–500 oC) over micro/mesoporous platinated catalysts has been investigated about activity, selectivity to CO2 and CO, catalyst's stability versus coke deposition and reaction kinetics. Kinetic of toluene oxidation was measured under various oxygen and toluene pressures and als...
Compositions of Al2O3+Si, SiO2+Al and Al+Si systems were prepared to study the effect of reaction bonding process on the mullite formation. The composition of each system was adopted according to mullite stoichiometery and sintered in 700-1600°C range. Results showed that the formation of reaction bonded mullite starting from Al2O3+Si mixtures, proceeded in two partially overlapping steps, the ...
background and objectives: safflower (carthamus tinctorious l.) florets contain valuable red and yellow pigments and are used in food, textile dying, and pharmaceutical industries. red carthamine pigment is formed from a yellow precursor, precarthamine, through an oxidation reaction at the end of flowers' maturation stage. the present study was conducted to find out the most effective procedure...
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