In this study, the use of the three-layer feed forward neural network has been investigated for estimating of infinite dilute diffusion coefficient ( D12 ) of supercritical fluid (SCF), liquid and gas binary systems. Infinite dilute diffusion coefficient was spotted as a function of critical temperature, critical pressure, critical volume, normal boiling point, molecular volume in normal boilin...

As the oven temperature is raised at a reproducible rate, analytes are eluted and the areas under the chromatogram are recorded. Boiling points are assigned to the time axis from a calibration curve, known as the boiling-point distribution curve, based on a known mixture of normal paraffin hydrocarbons over a fixed range. These paraffin hydrocarbons serve as markers, which identify the time tha...

The connectivity index chi can be regarded as the sum of bond contributions. In this article, boiling point (bp)-oriented contributions for each kind of bond are obtained by decomposing the connectivity indices into ten connectivity character bases and then doing a linear regression between bps and the bases. From the comparison of bp-oriented contributions with the contributions assigned by ch...

the relationship between the randic , wiener, hosoya , balaban, schultz indices, harary numbers anddistance matrix to enthalpies of formation (airf), heat capacity, (cp) , enthalpies of combustion (ah °c ),enthalpy of vaporization (ah °vap) and normal boiling points (bpk)of c2 c10 normal alkanes isrepresented

The relationship between the Randic , Wiener, Hosoya , Balaban, Schultz indices, Harary numbers andDistance matrix to enthalpies of formation (Airf), heat capacity, (Cp) , enthalpies of combustion (AH °c ),enthalpy of vaporization (AH °vap) and normal boiling points (bpK)of C2 C10 normal alkanes isrepresented

The heat of vaporization of a pure substance at its normal boiling temperature is a very important property in many chemical processes. In this work, a new empirical method was developed to predict vaporization enthalpy of pure substances. This equation is a function of normal boiling temperature, critical temperature, and critical pressure. The presented model is simple to use and provides an ...

The boiling points, rates of change of boiling point with pressure, and densities of methyl acetate, ethyl acetate, n-propyl acetate, and n-butyl acetate were measured by precise comparative methods using water as the reference standard . As in previous work on the normal saturated hydrocarbons and normal aliphatic alcohols, it was found that the introduction of each CH2 group into the chain of...