thin films of polymer doped with nonlinear optical organic dye, disperse red 1, at thickness of 1 to 2 micrometers, were prepared and studied. in order to induce an axial and orientational alignment of dye molecules within polymer matrix, a contact electric field poling was used. by this process the inherent inversion symmetry in the polymer matrix was eliminated to achieve the desired macrosco...

application of polymers in novel and advanced scientific technologies is increasingly expanding. in this regard, optical polymers among different materials have found a special and unique position. a novel dye doped polymer thin film was prepared by taking advantage of dye molecules' interaction with the host environment. this sample, like self-assembled structures, makes use of this inter...

A novel liquid dye 2-((2E,5E)-2,5-bis(4-(methyl(2,5, 8,11-tetraoxatridecan-13-yl)amino)benzylidene)cyclopentylidene) malononitrile (TO-BDCM) was synthesized by incorporating two oligo(ethenyl glycol) groups into the backbone of a prototype malononitrile derivative (BDCM) for the purpose of increasing its solubility in organic solvents. The nonlinear absorption properties of this liquid dye on 1...

Interactions between nonlinear optical organic dyes and assmblies of noble-metal nanostructures may potentially be exploited for optical-switching applications. Our focus has been on studying fundamental aspects of the interactions between conjugated molecules and noble metals. Aus nanoparticles (ca. 3 nm in diameter) coated with bis(diarylamino)biphenyl-based thiols with two different alkyl sp...

We investigate the time-dependent nonlinear optical absorption of a clay dispersion (Laponite) in an organic dye (rhodamine B) water solution displaying liquid-arrested state transition. Specifically, we determine the characteristic time tauD of the nonlinear susceptibility buildup due to the Soret effect. By comparing tauD with the relaxation time provided by standard dynamic light scattering ...

Exciton-polaritons are quasiparticles consisting of a linear superposition of photonic and excitonic states, offering potential for nonlinear optical devices. The excitonic component of the polariton provides a finite Coulomb scattering cross section, such that the different types of exciton found in organic materials (Frenkel) and inorganic materials (Wannier-Mott) produce polaritons with diff...

We carry out wavelength-dependent second harmonic interference experiments using thin films of an organic dye as nonlinear optical sources. While the measured difference of refractive index between the fundamental and second harmonic wavelengths follows the theoretical expectation for air in a wide spectral region, anomalous dispersion is observed when the second harmonic light lies in the abso...

The adsorption and orientation of a dye molecule to a planar, glass-supported phospholipid bilayer, a widely-used model membrane for biological studies, was measured with second harmonic spectroscopy. The results indicate that the positively charged dye binds at an angle of 19 degrees from the normal to the membrane plane. These results open the possibility of obtaining structural information o...

We have investigated third order nonlinear optical properties and spectral characteristics of methylene blue dye in both polymer and liquid mixtures. The spectral characteristics of the dye is studied by recording the absorption and fluorescence spectra of the dye doped in poly(methylmethacrylate) modified with additive n-butyl acetate(nBA) and the dye in MMA and nBA (liquid mixture). The spect...

In this paper we designed and prepared three free-metal organic days Dye 1, Dye 2 and Dye 3 based on indoline with n-phenly substituents iminodibenzyl as the electron donor group. We used cyanoacrylic acid substituent as the electron acceptor anchoring group in organic dyes. The proposed dyes were prepared from iminodibenzyl as the starting material by standard reactions and characterized by di...