The excellent bifunctional catalytic activity of nickel phosphide (Ni2P) for water splitting is reported. Ni2P, an active hydrogen evolving catalyst, is shown to be highly active for oxygen evolution. Only 290 mV of overpotential is required to generate a current density of 10 mA cm(-2) in 1 M KOH. Under oxygen evolving conditions, Ni2P undergoes structural modification to form a Ni2P/NiOx core...

Ni2P has been decorated on CdS nanowires or nanorods for efficient photocatalytic H2 production, whereas the specific surface area remains limited because of the large size. Here, the composites of Cd0.5Zn0.5S quantum dots (QDs) on thin Ni2P porous nanosheets with high specific surface area were constructed for noble metal-free photocatalytic H2 generation. The porous Ni2P nanosheets, which wer...

We present insights into the mechanism and the active site for hydrogen evolution on nickel phosphide (Ni2P). Ni2P was recently discovered to be a very active non-precious hydrogen evolution catalyst. Current literature attributes the activity of Ni2P to a particular site on the (0001) facet. In the present study, using Density Functional Theory (DFT) calculations, we show that several widely a...

Optimizing catalysts for the hydrogen evolution reaction (HER) is a critical step toward the efficient production of H2(g) fuel from water. It has been demonstrated experimentally that transitionmetal phosphides, specifically nickel phosphides Ni2P and Ni5P4, efficiently catalyze the HER at a small fraction of the cost of archetypal Pt-based electrocatalysts. However, the HER mechanism on nicke...

[1] High-pressure and high-temperature behavior of synthetic Ni2P has been studied in a laser-heated diamond anvil cell up to 50 GPa and 2200 K. Incongruent melting associated with formation of pyrite-type NiP2 and amorphous Ni-P alloy was found at an intermediate pressure range, between 6.5 and 40 GPa. Above 40 GPa, Ni2P melts congruently. At room conditions, Ni2P has hexagonal C22-type struct...

The depolymerization of lignin to bioaromatics usually requires a hydrodeoxygenation (HDO) step to lower the oxygen content. A mixed Cu-Mg-Al oxide (CuMgAlO x ) is an effective catalyst for the depolymerization of lignin in supercritical ethanol. We explored the use of Ni-based cocatalysts, i.e. Ni/SiO2, Ni2P/SiO2, and Ni/ASA (ASA = amorphous silica alumina), with the aim of combining lignin de...

Polydispersed dinickel phosphide (Ni2P) nanoparticles were synthesized by a simple and scalable solid-state reaction. These nanoparticles are an excellent and robust catalyst for the electrochemical hydrogen evolution reaction, operating in both acidic and basic solutions.

Efficient, low-cost, and stable electrocatalysts for water splitting are highly desirable. Herein, three-dimensional (3D) Ni2P nanosheet arrays were fabricated simultaneously modulated by heterostructure engineering Mn doping (Mn-doped Ni2O3/Ni2P Mn-doped NixSy/Ni2P) via a facile hydrothermal reaction subsequent phosphorization sulfurization. Due to the doping, synergistic effect in heterostruc...

In this paper, a novel Ni2P/black phosphorus (Ni2P/BP) supported on two-dimensional ?-zirconium phosphate (?-ZrP) hybrid material was prepared, and its catalytic activity for hydrodesulfurization (HDS) investigated. Through the reaction of nickel salt with BP nanosheets obtained by freeze-assisted exfoliation method, Ni2P nanoparticles can be formed firmly anchored surface BP, effectively preve...

For the first time, noble-metal-free nickel phosphide (Ni2P) was used as an excellent catalyst precursor for water oxidation catalysis. The lowest onset potential was observed at ∼1.54 V (vs. RHE) and a Tafel slope of 60 mV dec(-1) was obtained in alkaline solution (pH = 13.6).