Nano-Sn/C composites are ideal anode materials for high energy and power density Li-ion batteries. However, because of the low melting point of Sn and the tendency of grain growth, especially during high temperature carbonization, it has been a significant challenge to create well-dispersed ultrasmall Sn nanoparticles within a carbon matrix. In this paper, we demonstrate an aerosol spray pyroly...

A giant amphiphile, which is constructed with an amorphous nano-pyramid (triphenylamine, TPA) and a crystalline nano-sphere (C60), was synthesized. Structural characterization indicates that this pyramid-sphere-shaped amphiphile (TPA-C60 ) forms a solvent-induced ordered phase, in which the two constituent units self-assemble into alternating stacks of two-dimensional (2D) TPA and C60 nano-shee...

The collective wave type plasmon polariton self-modes in the metallic (Au, Ag) nano-chain were determined and analyzed with respect to the nano-sphere size and chain separation parameters. At some regions for parameters, the undamped modes were identified when the interaction had been assumed as the near-field-zone dipole coupling. These modes were found on the rim of stability of the linear th...

We report on the evolution of a hollow sphere secondary structure of spherical nanoparticles by a solubilization-reprecipitation mechanism based on the difference of solubility products (K(sp)) of two different precipitates. Carbon-coated nanoparticles of olivine structure LiFePO(4) served as the primary nano-blocks to build the secondary nano-architecture.

With using the carbon nano-tube (CNT) of high chemical activity, nano-TiCx particles with different growth shapes were synthesized through the self-propagating high temperature in the 80 wt.% metal (Cu, Al, and Fe)-Ti-CNT systems. The growth shapes of the TiCx particles are mainly octahedron in the Cu- and Al-Ti-CNT systems, while mainly cube- and sphere-like in the Fe-Ti-CNT system.

We introduce a forward model for the computation of high angle annular dark field (HAADF) images of nano-crystalline spherical particles and apply it to image simulations for assemblies of nano-spheres of Al, Cu, and Au with a range of sizes, as well as an artificial bi-sphere, consisting of solid hemispheres of Al and Cu or Al and Au. Comparison of computed intensity profiles with experimental...

The intrinsic low conductivity of sulfur which leads to a low performance at a high current rate is one of the most limiting factors for the commercialization of lithium-sulfur battery. Here, we present an easy and convenient method to synthesize a mono-dispersed hollow carbon sphere with a thin graphitic wall which can be utilized as a support with a good electrical conductivity for the prepar...

A new pathway to nano-sized hollow-sphere particles from six-arm star polymers with an amphiphilic core-corona structure, synthesized in a four-step-procedure by means of reversible addition-fragmentation chain transfer (RAFT) polymerization is presented, in order to achieve more stable and versatile nano-container systems, which could be applied in the fields of drug delivery or catalyst stora...

We investigated the As(III) and As(V) adsorption complexes forming at the gamma-Al(2)O(3)/water interface as a function of pH and ionic strength (I), using a combination of adsorption envelopes, electrophoretic mobility (EM) measurements, and X-ray absorption spectroscopy (XAS). The As adsorption envelopes show that (1) As(III) adsorption increases with increasing pH and is insensitive to I cha...