manganese metal-organic framework (mn-mof) containing mn2+ ions, benzenetricarboxylic acid (btc) and n,n-dimethylformamid (dmf) was prepared and used as catalyst for oxidation of alkenes such as 1,1-diphenylethylene, trans-stilbene, cyclohexene, norbornene, styrene and cyclooctene to epoxides with 33-92% conversion and 75-100% selectivity and oxidation of alkanes such as fluorene, adamantane, e...

An Mn metal-organic framework (Mn-MOF), Mn-L, based on a pyrene-tetraacid linker (H4 L), displays a respectable fluorescence quantum yield of 8.3% in spite of the presence of the paramagnetic metal ions, due presumably to fixation of the metal ions in geometries that do not allow complete energy/charge-transfer quenching. Remarkably, the porous Mn-L MOF with ∼25% solvent-accessible volume exhib...

Manganese metal-organic framework (Mn-MOF) containing Mn2+ ions, benzenetricarboxylic acid (BTC) and N,N-dimethylformamid (DMF) was prepared and used as catalyst for oxidation of alkenes such as 1,1-diphenylethylene, trans-stilbene, cyclohexene, norbornene, styrene and cyclooctene to epoxides with 33-92% conversion and 75-100% selectivity and oxidation of alkanes such as fluorene, adamantane, e...

Hybrid quantum mechanics/molecular mechanics (QM/MM) methods were employed to study electronic effects of 5,5'-substituents on the enantioselectivity of (salen)Mn catalysts. Correlations obtained from the QM/MM calculations elucidated electronic framework effects on enantioselectivity for (salen)Mn heterogenized in a metal-organic framework (MOF). The correlations also enabled fast ligand scree...

copper trimesate (cu-btc) mof has been pointed out as a promising adsorbent for separating carbon dioxide from methane. however, mof’s need to be shaped prior to their use in packed bed adsorbers in order to reduce pressure drop; on the other hand, the production of mechanically resistant shaped bodies reduces their adsorption performance. in this work, cu-btc tablets provided by basf are evalu...

In this paper, the effect of nanocatalytic metal-organic framework based on copper metal and bis-tetrazolamine (CuBTA) ligand functionalized with cobalt (II) oxide nanoparticles on the thermal decomposition behavior of ammonium perchlorate (AP), using differential survey calorimetry (DSC) has been reviewed. First, the metal-organic framework (CuBTA) was synthesized from the raw materials of cop...

photocatalytic degradation of toxic organic compound in water, soil and air by semiconductor catalysts such as tio2 and zno have received much attention over the last two decades. however, the low quantum yield, easy agglomeration and difficult post-separation of these inorganic catalysts limit their application for large-scale applications. metal-organic frameworks (mofs) are the latest class ...

By coupling of Fe2O3@SiO2 particles with metal organic Framework (MOF) the magnetic MOF structure was fabricated. Precipitation and hydrothermal methods were applied for synthesis of core and MOF. Silver nanoparticles were deposited on nickel based metal organic framework surface and magnetic Fe2O3@SiO2@MOF@Ag was obtained. Because of strong coupling between silver nanoparticles and metal organ...

We employed multiwavelength anomalous X-ray dispersion to determine the relative cation occupation at two crystallographically distinct metal sites in Fe-, Cu-, and Zn-exchanged versions of the microporous metal−organic framework (MOF) known as MnMnBTT (BTT = 1,3,5-benzenetristetrazolate). By exploiting the dispersive differences between Mn, Fe, Cu, and Zn, the extent and location of cation exc...

A new microporous metal-organic framework compound featuring chiral (salen)Mn struts is highly effective as an asymmetric catalyst for olefin epoxidation, yielding enantiomeric excesses that rival those of the free molecular analogue. Framework confinement of the manganese salen entity enhances catalyst stability, imparts substrate size selectivity, and permits catalyst separation and reuse.