soil can register environmental pollution in itself, so the pollution of an area can be studied through the chemical analysis of its soil. in the present study, the soil ofmellatparkintehranwas sampled. in total, 15 soil samples were collected. using laboratory methods, the mean concentration of pb, zn, and ni were obtained to be 145, 33, and 62 mg/kg, respectively. the results show that the co...

Proteolytic studies of rat liver metallothionein reconstituted in vitro with Cu salts revealed that the 2 metal centers fill in an ordered fashion. The B cluster in the NH2-terminal beta domain fills prior to Cu binding in cluster A. This is in contradistinction to cluster formation induced by the binding of Cd or Zn ions in which cluster A is the center of initial binding. The formation of met...

The cluster compounds (NH4)4[Nb6Cl12(N3)6](H2O)2 (1) and Na1.15(3)La0.85(3)[Nb6Cl12(N3)6](H2O)13(1) (2) have been synthesized by the reaction of an aqueous solution of Nb6Cl14 with an excess of NaN3 and the respective chloride salts. 1 crystallizes isotypically to the other alkali metal cluster azides in the space group P1̄ (no. 2) with the lattice parameters a = 908.97(8), b = 932.78(8), c = 10...

We report on the first observation of isolated large neutral metal amino acid complexes such as Trp(n)Me(k), with Me=Ca, Ba, Sr, cluster combinations covering n=1...33, k=0..2 and masses beyond 6500 u. The cluster beam is generated using UV laser desorption from a mixed powder of alkaline-earth metal salts and tryptophan inside a cluster mixing channel. The particles are detected using VUV phot...

The performance of a new pulsed arc cluster ion source (PACIS) is demonstrated for pure metal cluster ions and anions as well as mixed metal-rare-gas clusters. Pure metal clusters like W$ exhibit intensity distributions similar to those from laser vaporization sources. The ion current of the PACIS is comparable to that of a laser vaporization source. For metal-doped argon cluster ions, a single...

studies have showed the river siahroud is the main contributor to the present pollution of anzali wetland in guilan. therefore, this study was initiated to evaluate the spatial distribution of metals pollution on the river siahroud sediments in guilan.surfacial river sediment samples along this river were taken during five consecutive seasons at eight sampling stations and analyzed for availabi...

A new look at globular cluster colors in NGC 3311 and the case for exclusively metal–rich globular cluster systems ABSTRACT NGC 3311, the central cD galaxy in the Hydra cluster, was previously thought to host the most metal–rich globular cluster system known. Ground–based Washington photometry had indicated the almost complete absence of the population of globu-lar clusters near [Fe/H] ∼ −1 dex...