the melt-phase synthesis of dioctyltin (iv) and triphenyltin (iv) benzoates were carried outusing stoichiometric amounts of benzoic acids and the corresponding organotin (iv) compounds.the reagents were ground together in a mortar and fed into a boiling glass tube. a cannula tubewas inserted into the boiling tube to discharge accumulated gaseous products. a syringe ensureda continuous flow of d...

the rapid melting of a semi- infinite body due to the absorption of a cw laser beam radiation has been studied. the enthalpy technique for the solution of phase change problems has been used in an explicit finite difference form to calculate the transient temperature distribution in the semi-infinite body and the growth rate of the melt pool. the technique has been modified so that it is not ne...

The melt-phase synthesis of dioctyltin (IV) and triphenyltin (IV) benzoates were carried outusing stoichiometric amounts of benzoic acids and the corresponding organotin (IV) compounds.The reagents were ground together in a mortar and fed into a boiling glass tube. A cannula tubewas inserted into the boiling tube to discharge accumulated gaseous products. A syringe ensureda continuous flow of d...

The icosahedral quasicrystalline, amorphous plus crystalline and glassy phases were formed in Ti40Zr20Hf20(3d-LTM)20 alloys (3d-LTM=3d late transition metals Fe, Co and Ni). The icosahedral phase formed in the melt-spun Ti40Zr20Hf20Fe20 alloy is metastable and the average size of the quasicrystalline icosahedral particles precipitated in the amorphous matrix is 5 nm. The metastable icosahedral ...

the mechanism and the parameters affecting the matrix-fibril morphology in melt spun polyblend fibers are discussed. the properties of polymeric blends depend considerably on their final morphologies. blending of two miscible polymers, normally gives rise to formation of a single-phase morphology while blending of two immiscible polymers can create a two or three (in case of using compatibilize...

This paper presents a general overview of ow in deformable porous media with emphasis on melt extraction processes beneath mid-ocean ridges. Using a series of simple model problems, we show that the equations governing magma migration have two fundamentally different modes of behaviour. Compressible two-phase ow governs the separation of melt from the solid and forms a non-linear wave equation ...

[1] Anelasticity and diffusion creep viscosity of partially molten rock analogue were measured experimentally at various melt fractions (0.0025–0.04). The presence of even a small quantity of melt phase causes a significant increase in attenuation and dispersion, and decrease in viscosity (melt effect). Similar changes are additionally caused by the presence of a secondary solid component (chem...

In this study, the crystallization behavior of a 65GeO2-15PbO-10MgF2-10MgO glass (prepared by the conventional melt quenching technique) has been investigated. The microstructure and crystallization behaviors of this glass were characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), non-isothermal differential thermal analysis (DTA) and Fourier transform infrared spectr...

Functionalization of a cobalt/dioxolene complex with branched, asymmetric alkyl chains promotes non-cooperative and cooperative valence tautomerisms synchronized with thermodynamically favoured crystal-to-melt and kinetically generated glass-to-melt phase transitions, respectively, depending on the degree of crystallinity.

The temperature thawing, as called tempering, of triacylglycerols (TAGs) is an important processing method in food productions, such as chocolates, cream, confections, and spreads. Especially, melt-mediation by temperature thawing is famous in chocolate production for controlling the polymorphic crystalline forms and accelerating crystallization. In the present study, we investigated the α-melt...