We extend the results of Walters on the uniqueness of invariant measures with maximal entropy on compact groups to an arbitrary locally compact group. We show that the maximal entropy is attained at the left Haar measure and the measure of maximal entropy is unique.

A new concept named nonsymmetric entropy which generalizes the concepts of Boltzman’s entropy and shannon’s entropy, was introduced. Maximal nonsymmetric entropy principle was proven. Some important distribution laws were derived naturally from maximal nonsymmetric entropy principle.