نتایج جستجو برای: lanthanide

تعداد نتایج: 4165  

Journal: :iranian journal of chemistry and chemical engineering (ijcce) 2004
ram k. agarwal surendra prasad indranil chakraborti

lanthanide(iii) chloro complexes of 4[n-(4’-hydroxy-3’-methoxybenzalidene) amino] antipyrine semicarbazone (hmbaaps) (i) and 4[n-(3’,4’,5’-trimethoxybenzalidene) amino] antipyrine semicarbazone (tmbaaps) (ii) with the general composition lncl3.2l (ln = la, pr, nd, sm, gd, tb, dy or ho; l = hmbaaps or tmbaaps) are reported. all the complexes were synthesized in ethanolic medium and refluxed the ...

Journal: :Journal of the American Chemical Society 2008
Xun-Cheng Su Bradley Man Sophie Beeren Haobo Liang Shane Simonsen Christophe Schmitz Thomas Huber Barbara A Messerle Gottfried Otting

A new lanthanide tag was designed for site-specific labeling of proteins with paramagnetic lanthanide ions. The tag, 4-mercaptomethyl-dipicolinic acid, binds lanthanide ions with nanomolar affinity, is readily attached to proteins via a disulfide bond, and avoids the problems of diastereomer formation associated with most of the conventional lanthanide tags. The high lanthanide affinity of the ...

2014
Manoel A. M. Filho José Diogo L. Dutra Gerd B. Rocha Alfredo M. Simas Ricardo O. Freire

Complexes of dysprosium, holmium, and erbium find many applications as single-molecule magnets, as contrast agents for magnetic resonance imaging, as anti-cancer agents, in optical telecommunications, etc. Therefore, the development of tools that can be proven helpful to complex design is presently an active area of research. In this article, we advance a major improvement to the semiempirical ...

Journal: :Chemical Society reviews 2015
Hao Dong Ling-Dong Sun Chun-Hua Yan

Lanthanide pairs, which can upconvert low energy photons into higher energy photons, are promising for efficient upconversion emission. A typical system with Yb(3+) as a sensitizer can convert short NIR into visible/ultraviolet light via energy transfer between lanthanide ions. Such upconverting nanocrystals doped with lanthanide ions have found significant potential in bioimaging, photochemica...

Journal: :The Analyst 2011
Satoshi Shinoda Hiroshi Tsukube

Although lanthanide complexes are recently used in luminescence labeling of bio-targets, this review focuses on sensing profiles of synthetic and biological lanthanide complexes. Rational design and combinatorial screening approaches toward synthetic lanthanide complexes applicable as luminescent sensing materials are described. Iron-carrying transferrin and ferritin proteins further form lanth...

Journal: :Methods and applications in fluorescence 2014
Johanna Vuojola Tero Soukka

Lanthanides represent the chemical elements from lanthanum to lutetium. They intrinsically exhibit some very exciting photophysical properties, which can be further enhanced by incorporating the lanthanide ion into organic or inorganic sensitizing structures. A very popular approach is to conjugate the lanthanide ion to an organic chromophore structure forming lanthanide chelates. Another appro...

Journal: :Bioconjugate chemistry 2008
Pinghua Ge Paul R Selvin

Polyaminocarboxylate-based luminescent lanthanide complexes have unusual emission properties, including millisecond excited-state lifetimes and sharply spiked spectra compared to common organic fluorophores. There are three distinct sections in the structure of the luminescent lanthanide chelates: a polyaminocarboxylate backbone to bind the lanthanide ions tightly, an antenna molecule to sensit...

Journal: :Dalton transactions 2016
Marcel Kühling Robert McDonald Phil Liebing Liane Hilfert Michael J Ferguson Josef Takats Frank T Edelmann

Well-defined lanthanide polysulfide complexes containing S4(2-) and S5(2-) ligands, the samarium(iii) pentasulfide complex Sm(Tp(iPr2))(κ(1)-3,5-(i)Pr2Hpz)(S5) and the tetrasulfide-bridged binuclear ytterbium(iii) complex (μ-S4)[Yb(Tp(iPr2))(κ(1)-3,5-(i)Pr2Hpz)(κ(2)-3,5-(i)Pr2pz)]2 (Tp(iPr2) = hydro-tris(3,5-diisopropylpyrazolyl)borate), have been synthesized and structurally characterized by s...

2014
Murphy P. Fisher A. J. Roper J. K. Reynolds

The Mt Weld lanthanide deposit in central Western Australia is considered to be one of the largest high grade deposits known in the world, first reported as a carbonate and phosphate rich ultramafic silicate intrusion that contained a resource of the Lanthanide series [1]. It has been dated between 1.6 – 2.0 billion years, where the formation of a carbonate layer in the cooling melt created a p...

Journal: :Journal of photochemistry and photobiology. B, Biology 1995
E F Dickson A Pollak E P Diamandis

The principles and practice of the application of time-resolved lanthanide chelate luminescence (or fluorescence) as a detection method for ultrasensitive bioanalytical assays such as immunoassays and nucleic acid hybridization assays are reviewed. The various lanthanide chelate-based detection systems which have been developed for use in heterogeneous and homogeneous assay formats are describe...

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