based on driving force for crystallization of one-component gas hydrate, in this report an expression for the supersaturation for crystallization of multicomponent gas hydrate is derived. expressions for the supersaturation are obtained in isothermal and isobaric regimes. the results obtained are applied to the crystallization of hydrates of mixtures of methane plus ethane and can apply to othe...

gas hydrate formation in production and transmission pipelines and consequent plugging of these lines have been a major flow-assurance concern of the oil and gas industry for the last 75 years. gas hydrate formation rate is one of the most important topics related to the kinetics of the process of gas hydrate crystallization. the main purpose of this study is investigating phenomenon of gas hyd...

Understanding the kinetics of gas hydrate formation is essential to model and predict the hydrate formation (or dissociation) process. In the present paper, we investigated the formation of pure propane gas hydrate as a former gas. In this regard, several experiments were conducted to measure the rate of hydrate formation under various pressures (410 to 510 kPa) and temperatures (274 K to 277 K...

â  abstract: in this work, the kinetics of ethane hydrate formation has been studied experimentally and a kinetic model based on chemical affinity has been described for predicting the hydrate growth process in the stirred batch reactor at a constant volume. the experiments were done with both pure water and aqueous solution of sodium dodecyl sulfate (sds). the effect of sds on formation kineti...

this paper investigates the kinetics of structure h (sh) formation kinetics above and below the structure i (si) formation equilibrium curve at temperatures of between 2â°c and 6â°c. methane was used as a help gas and methylcyclohexane (mch) was used as sh former. it was concluded that in the points above the si formation equilibrium curve, at the first, the si forms, and then converts to sh be...

Gas hydrate formation in production and transmission pipelines and consequent plugging of these lines have been a major flow-assurance concern of the oil and gas industry for the last 75 years. Gas hydrate formation rate is one of the most important topics related to the kinetics of the process of gas hydrate crystallization. The main purpose of this study is investigating phenomenon of gas hyd...

Gas hydrate formation in production and transmission pipelines and consequent plugging of these lines have been a major flow-assurance concern of the oil and gas industry for the last 75 years. Gas hydrate formation rate is one of the most important topics related to the kinetics of the process of gas hydrate crystallization. The main purpose of this study is investigating phenomenon of gas hyd...

  Abstract: In this work, the kinetics of ethane hydrate formation has been studied experimentally and a kinetic model based on chemical affinity has been described for predicting the hydrate growth process in the stirred batch reactor at a constant volume. The experiments were done with both pure water and aqueous solution of sodium dodecyl sulfate (SDS). The effect of SDS on formation kineti...

In this study, the kinetics of gas hydrate formation in the presence of tetra-n-butyl ammonium fluoride (TBAF) and cetyl trimethyl ammonium bromide surface active ingredient (CTAB) with zinc nano oxide (ZnO) are investigated and the most important kinetic parameters of hydrate formation such as their induction time and storage capacity were measured. The kinetic experiments were carried out in ...

This paper investigates the kinetics of structure H (sH) formation kinetics above and below the structure I (sI) formation equilibrium curve at temperatures of between 2°C and 6°C. Methane was used as a help gas and methylcyclohexane (MCH) was used as sH former. It was concluded that in the points above the sI formation equilibrium curve, at the first, the sI forms, and then converts to sH be...