non-isothermal crystallization kinetics of polypropylene (pp) and pp containing 0.5 wt% singlewalled carbon nanotubes (pp/swnt) were studied at various cooling rates using differential scanning calorimetry technique. the non-isothermal melt crystallization data were analyzed according to ozawa and cazé-chuah models. although ozawa model was successful in describing the nonisothermal crystalliza...

poly(ethylene adipte) and poly(ethylene adipate)/silica nanocomposite (pead/sio2) containing 3 wt. % sio2  were prepared by an in situ method. the examinations on the non-isothermal crystallization kinetic behavior have been conducted by means of differential scanning calorimeter (dsc). the avrami, ozawa, and combined avrami and ozawa equations were applied to describe the crystallization kinet...

The green blends of an ionic liquid, 1-ethyl-3-propylimidazolium bis(trifluoromethanesulfonyl) imide {[EPrI][TFSI]}, and a biodegradable polymer, poly(3hydroxybutyrate) (PHB), were investigated in this study. The influence of an ionic liquid on the crystallization behaviors of a biodegradable polymer was explored. In the blends, the presence of [EPrI][TFSI] decreased the Tg and Tm of PHB. Incor...

Isothermal melt crystallization kinetics of PVDF was investigated by differential scanning calorimetry. Thin PVDF film has been fabricated by the solvent casting technique using dimethylformamide (DMF). Then, the samples were melted and subsequently crystallized in the range of the crystallization temperature (Tc) between 138 and 145 °C. The crystallization kinetics was derived from Avrami equa...

based on driving force for crystallization of one-component gas hydrate, in this report an expression for the supersaturation for crystallization of multicomponent gas hydrate is derived. expressions for the supersaturation are obtained in isothermal and isobaric regimes. the results obtained are applied to the crystallization of hydrates of mixtures of methane plus ethane and can apply to othe...

Non-isothermal crystallization of neat high density polyethylene (HDPE), wood flour (WF)/HDPE composite (WPC), virgin Kevlar fiber (KF) reinforced WPC (KFWPC), and grafted Kevlar fiber (GKF) reinforced WPC (GKFWPC) was investigated by means of differential scanning calorimetry (DSC) and wide angle X-ray diffraction (WAXD). Several theoretical models were applied to describe the process of nonis...

The nanophase structure of semicrystalline polymers, which determines the mechanical, thermal, and gas permeability behavior, can be quantified by thermal methods. A detailed investigation of the nanophase structure of poly[(R)-3-hydroxybutyrate] (PHB) was performed under conditions of isothermal, quasi-isothermal, and nonisothermal crystallizations. The experimental analyses revealed that the ...

Based on driving force for crystallization of one-component gas hydrate, in this report an expression for the supersaturation for crystallization of multicomponent gas hydrate is derived. Expressions for the supersaturation are obtained in isothermal and isobaric regimes. The results obtained are applied to the crystallization of hydrates of mixtures of methane plus ethane and can apply to ...

The characterization of the crystallization kinetics of an amorphous soft magnetic alloy, Fe88Zr7B4Cu1, called NANOPERM, is presented. Vibrating sample magnetometry (VSM), X-ray diffractometry, and differential scanning calorimetry have been used to observe crystallization kinetics. The VSM observations take advantage of the Curie temperature of the amorphous phase c amorphous of the NANOPERM a...

The crystallization process in Se100–xZnx glassy system is investigated using differential scanning calorimeters (DSC). The samples are prepared by conventional melt-quenching technique in the composition range 2 ≤ x ≤ 20 (at%). Nonisothermal measurements are carried out for different heating rates .The value of the glass transition temperature Tg the crystallization temperature Tc and the crys...