Chlorine is usually combined with inorganic compounds, such as sodium or calcium, to produce hypochlorites, which are effective disinfectants. Chlorine mixed with sodium is a liquid bleach known as sodium hypochlorite NaOCl. Chlorine mixed with calcium is usually in granular or tablet form and is called calcium hypochlorite Ca(OCL)2. Chlorine may also be available as chlorine dioxide (ClO2). Ho...

On-demand organic hypochlorites for the neutralization of sulfur-based chemical warfare simulants.

We have designed a chemodosimeter DPNO (weak fluorescence) which can be oxidized to HPNO (strong blue fluorescence) by OCl(-) with high selectivity and sensitivity in a ratiometric approach with a noticeably lower detection limit. The sensor could be useful for the detection of hypochlorites in tap water.

Hypochlorites efficently dehydrate hydroperoxyacetals to furnish the corresponding esters. The reaction, which can be accomplished with stoichometric Ca(OCl)(2) or with catalytic amounts of t-BuOCl, appears to involve formation and heterolytic fragmentation of secondary chloroperoxides, species not previously described in solution chemistry.