background and aims. adhesive permeability is hindered by application of an additional layer of hydrophobic resin, which increases its concentration within the hydrophilic layer, reduces its affinity to water, and enhances its physical properties. the aim of the present study was to evaluate the effect of a hydrophobic layer on the microleakage of class v composite restorations using different ...

objectives: composite repair is a minimally invasive and conservative approach. this study aimed to evaluate the effect of an additional hydrophobic resin layer on the repair shear bond strength of a silorane-based composite repaired with silorane or methacrylate-based composite. materials and methods: sixty bar-shaped composite blocks were fabricated and stored in saline for 72 hours. the surf...

In this work, the hydrophobic modification of TiO2 nanoparticles (HTiO2) was carried out by reacting with dodecylphosphonic acid (DDPA) and hexylamine solution. A facile approach of the self-assembly technique was used for the coating of hydrophobic HTiO2 layer over the microporous polypropylene (PP) membrane. The self-assembled layer was formed between the interface of trimesoyl chloride (TMC)...

The so-called island model of protein structural transition holds that hydrophobic interactions are the key to both the folding and function of proteins. Herein, the genesis and statistical mechanical basis of the island model of transitions are reviewed, by presenting the results of simulations of such transitions. Elucidating the physicochemical mechanism of protein structural formation is th...

Sophisticated manipulation of surface roughness and solid surface energy are widely used to design super-hydrophobic layers. In this work, we designed highly porous silica layer with contact angle (CA) of 145°, and its robustness was promoted with thermal treatment. Wettability of coated layer is studied with CA measurement for different liquid surface tensions using diluted organi...

Triple emulsion drops with an ultrathin water layer are developed to achieve high encapsulation efficiency of hydrophobic cargo in a hydrophobic polymeric shell, directly dispersed in water. Furthermore, enhanced retention of volatile hydrophobic cargo is achieved by forming a hydrogel network within this water layer that serves as a physical barrier.

In this paper we present a monolithic fabrication process for microcapillary sys tems that permits the formation of stable, photo-definable hydrophobic ( ) and hydrophilic ( ) regions on plastic channels. Using this process we have demonstrated a simple injector that uses a hydrophobic patch for cutting and transporting sample drops. Hydrophobic regions are formed by coating the inner walls wit...

Cationic amphiphilic diblock copolymers were synthesized by RAFT polymerization and the nanostructure of their monolayers was investigated by π-A isotherm and X-ray reflectivity. Carpet layer (dense hydrophilic block layer) formation under the hydrophobic layer was confirmed and a “brush” layer was found beneath the carpet layer. However, the thickness of brush layer was much thinner than that ...