Article history: Received 17 October 2007 Received in revised form 11 February 2008 Accepted 26 February 2008 Available online 14 April 2008 Humin is an important fraction of soil organic matter that is known to tightly bind many organic compounds. The objective of this study was to evaluate the role of humin as a natural sorbent in soils irrigated with freshwater and treated wastewater. To mee...

Humin is the most recalcitrant and least understood fraction of soil organic matter. By definition, humin is that fraction not extracted by traditional aqueous alkaline soil extractants. Here we show that > or = 70% of the traditional humin fraction is solubilized when 0.1 M NaOH + 6 M urea and dimethyl sulfoxide (DMSO) + 6% H2SO4 are used in series after conventional extraction. Multidimension...

the adsorption thermodynamic characteristic of cu2+ from aqueous solution onto humin andalso humic acid from a typical black soil in northeast china were examined at three different temperatures(298, 318 and 338 k) by batch isotherm experiments. results showed that humin was structurally differentfrom humic acid. the increase of temperature had a positive effect on the adsorption process. freun...

Cultures of the pyrene degrading Mycobacterium sp. KMS were incubated with [4-13C]pyrene or [4,5,9,10-14C]pyrene with and without a soil humic acid standard to characterize the chemical nature of the produced residues and evaluate the potential for bonding reactions with humic acid. Cultures were subjected to a "humic acid/ humin" separation at acidic pH, a duplicate separation followed by solv...

Batch and column experiments were performed to determine the Cu(II) binding capacity of silica-immobilized humin biomass. For column studies, 500 bed volumes of a 0.1 mM Cu(II) solution were passed through humin packed columns at the flow rates of 1, 1.5, 2, and 3 mL/min. The biopolymer showed an average Cu binding capacity of 12 +/- 1.5 mg/g and a Cu recovery of about 96.5 % +/- 1.5. The break...

We present and compare AMS-C geochronologies for sediment cores recovered from Lake Titicaca, South America. Radiocarbon dates from three core sites constrain the timing of late Quaternary paleoenvironmental changes in the Central Andes and highlight the site-specific factors that limit the radiocarbon geochronometer. With the exception of mid-Holocene sediments, all cores are generally devoid ...

Peroxidase enzymes can enhance the rate and extent of contaminant binding to soil organic matter and immobilize the contaminant within the soil matrix, and thus prevent its transport into the subsurface. This study focused on evaluating the binding of phenol, dichlorophenol, and naphthol, individually and as mixtures, on two sandy loams belonging to the Haynie series. U-ring-14 C-labeled target...