thermal cracking of a heavy liquid hydrocarbon was performed in a laboratory scale tubular reactor. central composite design (ccd), was used as an experimental design method. the design variables were coil outlet temperature (cot), feed flow and rate steam ratio. maximum yield of ethylene was 30.37 wt% at cot, residence time and steam ratio of 869oc, 0.208 s and 1.22 g/g, respectively. maximum ...

We apply a cubic-plus-association equation of state (CPA-EOS) to study the asphaltene precipitation in live oils from temperature, pressure, and composition effects. The live oils are characterized by considering the pure components, the pseudo-hydrocarbon components, and the hydrocarbon residue. The hydrocarbon residue is further divided into the “heavy” component and asphaltenes. The asphalte...

Hydrocarbon liquid dropout can cause a number of problems in gas transmission lines, including increased pressure drop, reduced line capacity, and equipment problems such as compressor damage. To avoid liquid dropout, most current operating specifications for gas transmission lines require that the lines be operated above the hydrocarbon dew point (HDP) or cricondentherm hydrocarbon dew point (...

Thermal cracking of a heavy liquid hydrocarbon was performed in a laboratory scale tubular reactor. Central Composite Design (CCD), was used as an experimental design method. The design variables were Coil Outlet Temperature (COT), feed flow and rate steam ratio. Maximum yield of ethylene was 30.37 wt% at COT, residence time and steam ratio of 869oC, 0.208 s and 1.22 g/g, respect...

A systematic study of two-staged upgrading process of vacuum residue for light fuel production has been carried out in a semi-batch binary reactor apparatus over Y, ZSM-5 and alkaline treated ZSM-5 zeolites. Prepared catalyst samples were characterized with XRD and BET. Density and Viscosity physical properties parameters estimation, as well as GC/SIMDIS analyses were conducted on liquid produc...

The purpose of this paper was to review and report the recent advances and progress that have been achieved on the fourteen year old PFGC equation of state. This paper will also discuss the good (pros) and the bad (cons) of this equation of state. Emphasis will be made on the following categories:A. Prediction of the pure component PVT properties1. Hydrocarbons in particular n-alkanes2. Selecte...

Coal, which is usually land plant in origin, occurs in many oil-producing basins. Microscopically, coal consists of various macerals (liptinite, vitrinite, and inertinite). The generative potential of coal reflects the hydrocarbon potential of the composing macerals (Kelly et al., 1985). Although most coals consist of predominantly vitrinite, some contain significant amounts (>20% of total mace...

Host molecules with U-shaped receptor cavities have been derivatized at their convex side with two n-hydrocarbon tails (1), two first-generation (2), and two second-generation (3) monodendritic hydrocarbon tails. Although hosts 1 and 2 display plastic-crystalline behavior, evidence suggests that host 3 forms a cubic liquid-crystalline phase. In this phase, molecules of 3 are arranged in spheric...

Heavy and extra heavy crude oils are forming tremendous part of world crudes (about 40%). There are some problems limiting accessibility as a galore hydrocarbon source. One of limiting process is transportation which consumes very huge amount of energy due to their high viscosity. So, if there were a simple, stable, practicable in each situation and environmental friendly solution, these hydroc...