an extensive study of fischer-tropsch synthesis (fts) on alumina-supported cobalt catalysts with different amounts of cobalt is reported. up to 40 wt % of cobalt, is added to the catalysts by impregnation method. the effect of the cobalt loading on the reducibility of the cobalt oxide species, dispersion of the cobalt, average clusters size, water-gas shift (wgs) activity and activity and selec...

kinetic modeling is an important issue, whose objective is the accurate determination of the rates of various reactions taking place in a reacting system. this issue is a pivotal element in the process design and development particularly for novel processes which are based on reactions taking place between various types of species. the fischer tropsch (ft) reactions have been used as the kineti...

background : the present study was undertaken to ascertain whether (or not) long term occupational exposure to low (sub-tlv levels) atmospheric concentrations of chlorine gas was associated with any significant decrements in the parameters of pulmonary function and/or  increased prevalence of respiratory symptoms. methods : in this retrospective cohort study that was performed in 2012, 54 worke...

A scale-up study has been performed with three different size reactors to establish the optimum operating conditions for the hydrogen production from synthesis gas by biological water-gas shift reaction using the photosynthetic bacterium Rhodosprilliunt rubrum. Optimum medium composition and operating conditions previously determined in a bench scale 1.25 L continuous stirred tank reactor (CSTR...

effect of water gas shift reaction (co+h2o=co2+h2) on wustite reduction has been investigated by a transient, non-isothermal mathematical model based on grain model. in this model, wustite porous pellet is reduced using syngas, namely a mixture of hydrogen, carbon monoxide, carbon dioxide and water vapor. for this purpose, governing equations containing continuity equation of species and energy...

a synthesis of well logs was carried out and drilling mud weight data were analyzed to figure outanomalous high fluid pressure within the triassic evaporitic cap rock (the dashtak formation) andstudy its impact on the geometry of anticlinal traps in the gas rich gavbandi province located in thesoutheast part of the zagros mountains. the results indicated that the location of anticlinal traps at...

in this work the kinetic data demanded for kinetic modeling were obtained in temperatures 350, 400, 450 and 500 oc by conducting experimentations on a fe-cr nanocatalyst prepared from a novel method and a commercial fe-cr-cu one. the collected data were subjected to kinetic modeling by using two models derived from redox and associative mechanisms as well as an empirical one. the coefficients o...