polymerization of styrene in presence of two monofunctional initiators is studied kinetically in an ampoule scale. polymerizations were ceased at different conversions for each ampoule while the temperature was increased almost linearly during the reaction. three different initiator mixtures were used. the first mixtures were composed of benzoil peroxide (bpo) and t-butyl perbenzoate (tbpb) wit...

introduction: different dosimetric modalities (e.g., ionization chambers, semiconductors, tlds, radiographic films) often have some problems determining isodose curves and percentage depth doses in high dose gradient regions. research has been ongoing to develop portable high resolution dosimetry devices with accurate absolute dosimetry capabilities and easy data analysis. the ‘presage’ dosimet...

Titanium dioxide (TiO2) nanoparticles, with an average size of about 45 nm, were encapsulated by polystyrene using in situ nitroxide mediated radical polymerization   in the presence of 3-aminopropyl triethoxy silane (APTES) as a coupling agent and 2, 2, 6, 6-tetramethylpiperidinyl-1-oxy  as a initiator. First, the initiator for NMRP was covalently bonded onto the surface of Titanium dioxide na...

Self-healing chemistry used for damage repair have not previously been demonstrated for free-radical polymerization pathways. However, this chemistry is important for addition polymers such as poly(methyl methacrylate) used in bone cement and epoxy vinyl ester used in dental resins. Self-healing biomaterials offer the potential for safer and longer lasting implants and restoratives by slowing o...

titanium dioxide (tio2) nanoparticles, with an average size of about 45 nm, were encapsulated by polystyrene using in situ nitroxide mediated radical polymerization   in the presence of 3-aminopropyl triethoxy silane (aptes) as a coupling agent and 2, 2, 6, 6-tetramethylpiperidinyl-1-oxy  as a initiator. first, the initiator for nmrp was covalently bonded onto the surface of titanium dioxide na...

acrylamide was grafted in low density polyethylene during melt processing in the presence of a free radical initiator using a torque rheometer in a closed system. effects of processing time, acrylamide and benzoyl peroxide concentrations were studied. ftir studies revealed that the degree of grafting increased by an increase in acrylamide concentration. maximum grafting was obtained at 7 minute...

Recently, we proposed an oxygen radical absorbance capacity method that directly quantifies the antioxidant's scavenging capacity against free radicals and evaluated the radical scavenging abilities for water soluble antioxidant compounds. In this study, we determined the radical scavenging abilities of lipophilic antioxidants which were solubilized by cyclodextrin in water. Commonly employed f...

We offer a mild, metal-free sp(3) C-H fluorination alternative using Selectfluor and a substoichiometric amount of triethylborane--an established radical initiator in the presence of O2. This radical-chain-based synthetic method is particularly noteworthy as an offspring of the insight gained from a mechanistic study of copper-promoted aliphatic fluorination, constructively turning O2 from an e...

Mechanochemical approaches are widely used for the efficient, solvent-free synthesis of organic molecules, however their applicability to functional polymers has remained underexplored. In Research Article (e202305783), Carsten Bolm, Andrij Pich, and co-workers developed a free-radical polymerization approach mechanochemically synthesize structurally morphologically well-defined complex macromo...

* Corresponding Author Email: [email protected] Objective(s): The main aim of current research was to develop a novel magnetically responsive hydrogel by radical polymerization of carboxymethyl cellulose (CMC) on acryl amide (Am) using N,N'-methylene bis acrylamide (MBA) as a crosslinking agent, potassium persulfate (KPS) as a free radical initiator, and magnetic montmorillonite ( mMT)...