this paper investigates the kinetics of structure h (sh) formation kinetics above and below the structure i (si) formation equilibrium curve at temperatures of between 2â°c and 6â°c. methane was used as a help gas and methylcyclohexane (mch) was used as sh former. it was concluded that in the points above the si formation equilibrium curve, at the first, the si forms, and then converts to sh be...

based on driving force for crystallization of one-component gas hydrate, in this report an expression for the supersaturation for crystallization of multicomponent gas hydrate is derived. expressions for the supersaturation are obtained in isothermal and isobaric regimes. the results obtained are applied to the crystallization of hydrates of mixtures of methane plus ethane and can apply to othe...

This paper investigates the kinetics of structure H (sH) formation kinetics above and below the structure I (sI) formation equilibrium curve at temperatures of between 2°C and 6°C. Methane was used as a help gas and methylcyclohexane (MCH) was used as sH former. It was concluded that in the points above the sI formation equilibrium curve, at the first, the sI forms, and then converts to sH be...

â  abstract: in this work, the kinetics of ethane hydrate formation has been studied experimentally and a kinetic model based on chemical affinity has been described for predicting the hydrate growth process in the stirred batch reactor at a constant volume. the experiments were done with both pure water and aqueous solution of sodium dodecyl sulfate (sds). the effect of sds on formation kineti...

context:in this review, we discuss empirical and stoichiometric models, which have been developed recently in ssf processes and the influence of environmental conditions on the variables of these models. additionally, new studies on modeling of product formation are also mentioned. evidence acquisition:solid-state fermentation (ssf) is recognized as a cheap process for producing many valuable p...

the kinetics of catalyst deactivation and coke formation during dehydrogenation of propane over supported pt–based catalysts and, in particular, the effect of alkali metal promoters on catalyst activity and stability were studied. the analysis of propane conversion data showed that there is an optimum level of alkali metal promoter loading for both catalyst activity and stability.a model based ...

Understanding the kinetics of gas hydrate formation is essential to model and predict the hydrate formation (or dissociation) process. In the present paper, we investigated the formation of pure propane gas hydrate as a former gas. In this regard, several experiments were conducted to measure the rate of hydrate formation under various pressures (410 to 510 kPa) and temperatures (274 K to 277 K...

The kinetics of catalyst deactivation and coke formation during dehydrogenation of propane over supported Pt–based catalysts and, in particular, the effect of alkali metal promoters on catalyst activity and stability were studied. The analysis of propane conversion data showed that there is an optimum level of alkali metal promoter loading for both catalyst activity and stability.A model ba...

  Abstract: In this work, the kinetics of ethane hydrate formation has been studied experimentally and a kinetic model based on chemical affinity has been described for predicting the hydrate growth process in the stirred batch reactor at a constant volume. The experiments were done with both pure water and aqueous solution of sodium dodecyl sulfate (SDS). The effect of SDS on formation kineti...