the kinetic of fischer-tropsch synthesis over a co-precipitated fe-ce catalyst was investigated in a fixed bed micro reactor. experimental conditions were varied as follow: reaction pressure 1-15bar, h¬¬¬2/co feed ratio of 1-3 and space velocity of 3600-5400 h-1 at the temperature range of 270-310°c. 4 models according to the langmuir-hinshelwood-hougen-watson (lhhw) type rate equation were der...

A series of Fe–Ce–Ti catalysts were prepared via co-precipitation method to investigate the effect of doping Ce into Fe–Ti catalysts for selective catalytic reduction of NO with NH3. The NO conversion over Fe–Ce–Ti catalysts was considerably improved after Ce doping compared to that of Fe–Ti catalysts. The Fe(0.2)–Ce(0.4)–Ti catalysts exhibited superior catalytic activity to that of Fe(0.2)–Ti ...

Using wet impregnation method, a novel ternary system of silica supported Fe-Co-Ce catalyst was prepared. Preparation conditions such as impregnation time and temperature, drying time and temperature, were optimized by the L9 Taguchi experimental design to achieve a light olefin selective catalyst with maximum CO conversion in a fixed bed micro-reactor. It was found that the best conditions to ...

methanol steam reforming plays a pivotal role to produce hydrogen for fuel cell systems in a low temperature range. to accomplish higher methanol conversion and lower co production, the reaction was catalyzed by cuznfe mixed oxides. various ratios of fe and cu/zn were coprecipitated in differential method to optimize the cuznfe structure. the sample containing 45cu50zn5fe (wt. %) revealed its m...

We report dynamic alternation of the redox chemistry of the Fe/ Fe couple in magnetite during high temperature water−gas shift reaction in Cu codoped Mmodified ferrite catalysts. Various hematitic solid solutions of the type Fe2O3−MxOy−CuOx with M = Cr, Ce, Ni, Co, Mn, and Zn are synthesized using the industrially economical and environmentally friendly coprecipitation method. Interestingly, Cu...

In this work the development of gold catalysts, essentially based on γ-alumina with small superficial fraction of Ce-Fe mixed oxides as support for the low temperature CO oxidation is proposed. Characterization results obtained by means of TEM, OSC, XPS, UV-Vis spectroscopy and H2-TPR are employed to correlate the activity data with the catalysts composition. The bare γ-alumina supported gold c...

0021-9517/$ see front matter 2011 Elsevier Inc. A doi:10.1016/j.jcat.2011.06.016 ⇑ Corresponding authors. Fax: +1 513 556 3473. E-mail addresses: [email protected] (P. Bool [email protected] (P.G. Smirniotis). High temperature water gas shift reaction (WGS) at low steam to CO ratios has been investigated over Fe2.4Ce0.3M0.3O4 (M = Cr, Co, Zr, Hf, and Mo) type of spinels in the temperature region of ...

The SiO2 supported cobalt-iron nano catalysts were prepared by the sol-gel method. This research investigated the effects of (Co/Fe) wt.%, different Co/Fe ratio at different temperature and loading of KCl wt.% for Fisher-Tropsch synthesis (FTS). The results were showed that the catalyst containing 50 wt.% (Co/Fe)/SiO2 (Co/Fe ratio is 70/30) which promoted with 0.6 wt.% KCl is an optimal nano ca...

nanometric carbid silicon (sic) supported monometallic and bimetallic catalysts containing fe, co, ni transition metals were prepared by wet impregnation method. multiwall carbon nanotubes (mwcnts) were synthesized over the prepared catalysts from catalytic decomposition of acetylene at 850°c by thermal chemical vapor deposition (tcvd) technique. the synthesized nanomaterials (catalysts and cnt...

Ce-Fe-Co-B is a promising system for permanent magnets. A high-throughput screening method combining diffusion couples, key alloys, Scanning Electron Microscope/Wavelength Dispersive X-ray Spectroscope (SEM/WDS), and Magnetic Force Microscope (MFM) is used in this research to understand the phase equilibria and to explore promising magnetic phases in this system. Three magnetic phases were dete...