heterogeneous proton exchange membranes (pem) are synthesized using the dry phase inversion technique. the casting solutions are prepared by dispersing a finely ground cation exchange resin particle in n,n-dimethylacetamide (dmac) solution of polyvinyl-chloride (pvc). results show that ion exchange capacity is increased with the addition of 1 %-wt nanosilica (from 0.14 to 0.27 meq/g) while it i...

the reported work is on the preparation and characterization of polyvinyl alcohol -g- polyacrylic acid (pva-g-paa)/ polybenzimidazole sulfone (pbis) cation exchange membrane used for the electro dialysis of sodium chloride solution. the polymer syrup has been prepared using the grafting method with the help of polyvinyl alcohol and polyacrylic acid in the presence of water solvent. the polymer ...

a pvc-based membrane containing cerium phosphate was developed. unlike the cerium phosphate itself that acts as a cation exchanger, the membrane exhibited anion-exchange properties. therefore, the utility of this compound as a sensory element for detection of molybdate ions was pursued. the response of molybdate selective electrode based on this membrane was perfectly linear in the concentratio...

sulfonated poly (ether ether ketone) (speek) with a low degree of sulfonation (ds = 40%) was prepared for proton exchange membrane fuel cells (pemfc). poly (ether ether ketone) (peek) was sulfonated in concentrated h2so4 under n2 atmosphere and characterized by the hydrogen nuclear magnetic resonance (h-nmr) technique. after preparation of the speek polymer, the obtained polymer was dissolved i...

in the current work, graphene oxide (go) samples were prepared at room temperature from graphite flakes using a modified hummer's method to produce metal-free electrocatalysts. the effect of the duration of the oxidation process on the structural, chemical and physical characteristics of the go samples was evaluated using x-ray diffraction (xrd), fourier transform infrared spectroscopy (ftir), ...

cyanide ion, is an environmentally significant pollutant in many industrial wastewaters.therefore, a considerable number of methods have been studied for the wastewater treatment containingcyanide. the goal of our work consists in applying a simple and economic process for solving this problem ofpollution. the removal of cyanide ions by using three anion exchange membranes has been studied unde...

in present research work, homogeneous anion exchange membranes based on polysulfone (qapsfs) were prepared via chloromethylation, amination and alkalization. in amination step, trimethylamine and n,n,n',n'-tetramethyl-1,6-hexanediamine were used as amination and crosslinking agents, respectively. the chloromethylated polysulfone was characterized by 1hnmr spectroscopy and chloromethylation degr...

in the current research, polyvinylchloride based mixed matrix heterogeneous anion exchange membranes were prepared by a solution casting technique. titanium dioxide nanoparticles were also utilized as inorganic filler additive in the membrane fabrication. the effect of tio2 nanoparticles concentration in the casting solution on the membrane physico-chemical properties was studied. membrane wate...

In this study, ion exchange nanocomposite membranes was prepared by addition of Mg(OH)2 nanoparticles to a blend containing sulfonated polyphenylene oxide and sulfonated polyvinylchloride via a simple casting method. Magnesium hydroxide nanoparticles were synthesized via a facile sono-chemical reaction and were selected as filler additive in fabrication of ion exchange nanocomposite membranes. ...

Heterogeneous proton exchange membranes (PEM) are synthesized using the dry phase inversion technique. The casting solutions are prepared by dispersing a finely ground cation exchange resin particle in N,N-dimethylacetamide (DMAc) solution of polyvinyl-chloride (PVC). Results show that ion exchange capacity is increased with the addition of 1 %-wt nanosilica (from 0.14 to 0.27 meq/g) while it i...