Capability of the Proper Orthogonal Decomposition (POD) method in extraction of the coherent structures from a spatio-temporal chaotic field is assessed in this paper. As the chaotic field, an ensemble of 40 snapshots, obtained from Direct Numerical Simulation (DNS) of the Kuramoto-Sivashinsky (KS) equation, has been used. Contrary to the usual methods, where the ergodicity of the field is need...