In this work, the performance of four electrolyte models for prediction the osmotic and activity coefficients of different aqueous salt solutions at 298 K, atmospheric pressure and in a wide range of concentrations are evaluated. In two of these models, (electrolyte Non-Random Two-Liquid e-NRTL and Mean Spherical Approximation-Non-Random Two-Liquid MSA-NRTL), association between ions of opposit...

In the present study, five modeling approaches of RA, MLP, MNN, GFF, and CANFIS were applied so as to estimate the radial overcut values in electrochemical drilling process. For these models, four input variables, namely electrolyte concentration, voltage, initial machining gap, and tool feed rate, were selected. The developed models were evaluated in terms of their prediction capability with m...

in the present study, five modeling approaches of ra, mlp, mnn, gff, and canfis were applied so as to estimate the radial overcut values in electrochemical drilling process. for these models, four input variables, namely electrolyte concentration, voltage, initial machining gap, and tool feed rate, were selected. the developed models were evaluated in terms of their prediction capability with m...

A new theoretical model based on the local composition concept (TNRF-mNRTL model) was proposed to express the short-range contribution of the excess Gibbs energy for the solutions containing polymer and electrolyte. This contribution of interaction along with the long-range contribution of interaction (Pitzer-Debye-Hückel equation), configurational entropy of mixing (Flory-Huggins relation)...

Introduction Conclusions References Tables Figures Back Close Abstract Introduction Conclusions References Tables Figures Back Close Abstract In this work, existing and modified activity coefficient models are examined in order to assess their capabilities to describe the properties of aqueous solution droplets relevant in the atmosphere. Five different water-organic-electrolyte activity coeffi...

Recent advances in modeling thermodynamic and transport properties of electrolyte solutions are reviewed. In particular, attention is focused on mixed-solvent electrolyte models, equations of state for high-temperature and supercritical electrolyte systems and transport property models for multicomponent, concentrated solutions. The models are analyzed with respect to their capability of comput...

Hot potassium carbonate (PC) solution in comparison with amine solution had a decreased energy of regeneration and a high chemical solubility of . To present vapor and liquid equation (VLE) of this system and predict  solubility, the ion specific non-electrolyte Wilson-NRF local composition model (isNWN) was used in this study; the framework of this model was molecular. Therefore, it was suitab...

In this work, existing and modified activity coefficient models are examined in order to assess their capabilities to describe the properties of aqueous solution droplets relevant in the atmosphere. Five different water-organicelectrolyte activity coefficient models were first selected from the literature. Only one of these models included organics and electrolytes which are common in atmospher...

Models that accurately predict solid–solute phase equilibria in aqueous electrolyte solutions are of mounting importance for numerous industrial processes, especially those operating at high temperatures, pressures, and concentrations. The incorporation of such electrolyte models into process simulators is in great demand. This communication will focus on thermodynamically consistent models tha...

In this study, the Langmuir adsorption isotherm has been coupled with activity coefficient models for prediction of surface tension of single and mixed electrolyte solutions. Various activity models such as Meissner, Pitzer and extended UNIQUAC have been used and coupled with Langmuir adsorption isotherm. The model parameters were determined through mathematical optimization using experimental ...