Eleonora Baldonero ([email protected]) Nicoletta Ciccarelli ([email protected]) Massimiliano Fabbiani ([email protected]) Manuela Colafigli ([email protected]) Erika Improta ([email protected]) Alessandro D’Avino ([email protected]) Annalisa Mondi ([email protected]) Roberto Cauda ([email protected]) Simona Di Giambenedetto (simona.digiambe...

Research group: Quantum Computing and Devices (QCD) Contact person: Dr. Mikko Möttönen ([email protected]) Field of research: Nanoelectronics and Quantum Computing Project title: Superconducting quantum computers: control of dissipation Project instructor: Dr. Jan Goetz, M.Sc. Matti Partanen, Dr. Vasilii Sevriuk, Dr. Jani Tuorila, Dr. Matti Silveri Site of research: Aalto University, QCD ...

a series of dissymmetric dinuclear complexes were synthesized, as dual site catalysts in ethylene polymerization,by coupling the allylated a-diimine complexes of the metals ti, zr, v, ni and pd with the ansa-zirconocenecomplex [c5h4-sih(me)-c5h4]zrcl2 possessing a hydride silane moiety. the different stages of syntheses includedthe formation of bis(cyclopentadienide)methyl silane which was util...

Research group: Quantum Computing and Devices (QCD) Contact person: Prof. Mikko Möttönen ([email protected]) Field of research: Nanoelectronics and Quantum Computing Project title: Superconducting quantum computers: control of dissipation Project instructor: MSc Matti Partanen, Dr. Kuan Yen Tan, Dr. Jani Tuorila, Dr. Matti Silveri Site of research: Aalto University, QCD group, Otaniemi We...

A series of dissymmetric dinuclear complexes were synthesized, as dual site catalysts in ethylene polymerization, by coupling the allylated a-diimine complexes of the metals Ti, Zr, V, Ni and Pd with the ansa-zirconocene complex [C5H4-SiH(Me)-C5H4]ZrCl2 possessing a hydride silane moiety. The different stages of syntheses included the formation of bis(cyclopentadienide)methyl silane which was u...

electrochemical behavior of the new mono and dinuclear co (iii)  complexes of  the types trans-[pyco((do)(doh)pn )(l)]pf6   and [{py co((do)(doh)pn)}2 (μ-dicyd)] (pf6)2   have been studied in acetonitrile solution.  all the  mono nuclear complexes  show two quasi- reversible reduction couples associate  to co(iii/ii)and  co(ii/i). each of these redox couples split to two  one electron  waves in...

J. Z. Blumoff, K. Chou, C. Shen, M. Reagor, C. Axline, R. T. Brierley, M. P. Silveri, C. Wang, B. Vlastakis, S. E. Nigg, L. Frunzio, M. H. Devoret, L. Jiang, S. M. Girvin, and R. J. Schoelkopf Department of Applied Physics and Physics, Yale University, New Haven, Connecticut 06511, USA Rigetti Quantum Computing, 775 Heinz Avenue, Berkeley, California 94710, USA Research Unit of Theoretical Phys...

Employing the oxidative coupling of phenylacetylene with benzaldehyde as a model reaction, a density functional theory (DFT) study combined with extended X-ray absorption fine structure (EXAFS) experiment was carried out to reveal the difference between dinuclear and mononuclear zinc mediated nucleophilic addition. Newly reported DFT method M11-L computed results suggest that the mononuclear zi...

The hydroxido-bridged dinuclear ruthenium complex 4, which is supported by Tp ligands, has been prepared from protonation of the oxido-bridged dinuclear ruthenium complex 3. Additional protonation of 4, affording the aqua-bridged dinuclear ruthenium complex 5 in situ, and subsequent treatment with NO gave rise to the dicationic dinitrosyl complex 2. These indicate completion of the NO reduction...

This Account summarizes the DNA binding properties of anticancer active dinuclear Rh, Re, and Ru compounds. The combined results of NMR spectroscopy, X-ray crystallography, and various biochemical tools provide incontrovertible evidence that dinuclear complexes are favorably poised to bind to purine nucleobases, DNA fragments, and double-stranded DNA. Moreover, direct DNA photocleavage in vitro...